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Alkane oxidation on isolated Cu2+ ions in zeolitic matrix: a relation between catalytic activity and Cu2+-site local topography

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Abstract

Catalytic ethane oxidation, with O2, using H-ZSM-5 and H-mordenite containing different discrete types of isolated Cu(II) cations was studied. An ESR spectroscopic study was carried out on copper ion coordination in zeolites. It was shown that the intrinsic activity of Cu(II) ion depends strongly on the Cu2+-site local topography. Covalent-bonded Cu(II) cations in the most coordinatively unsaturated square-planar coordination in H-ZSM-5 demonstrated the highest activity in C2H6 complete oxidation.

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Authors and Affiliations

  1. N.D. Zelinsky Institute of Organic Chemistry, USSR Academy of Sciences, Leninsky Prosp. 47, B-334, Moscow, USSR

    A. V. Kucherov, T. N. Kucherova & A. A. Slinkin

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  1. A. V. Kucherov
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  2. T. N. Kucherova
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  3. A. A. Slinkin
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Kucherov, A.V., Kucherova, T.N. & Slinkin, A.A. Alkane oxidation on isolated Cu2+ ions in zeolitic matrix: a relation between catalytic activity and Cu2+-site local topography. Catal Lett 10, 289–296 (1991). https://doi.org/10.1007/BF00772083

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  • DOI: https://doi.org/10.1007/BF00772083

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