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TPD/TPR and quantum chemical study of methanol interaction with H3+n PV n Mo12-n O40 heteropolyacids

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Abstract

Quantum chemical calculations of the electronic structure, charge distribution, bond lengths and angles have been carried out for different species involved in the transformation of methanol along acid-base and redox reaction pathways. Results are compared with the TPD/TPR measurements of methanol interaction with H3+nPVnMo12−nO40 heteropolyacids.

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References

  1. M. Misono, Catal. Rev.-Sci. Eng. 29 (1987) 269, and the references therein.

    Google Scholar 

  2. E.M. Serwicka, J.B. Black and J.B. Goodenough, J. Catal. 106 (1987) 23.

    Google Scholar 

  3. J.B. Monagle and J.B. Moffat, J. Catal. 91 (1985) 132 and the references therein.

    Google Scholar 

  4. Y. Ono, T. Mori and T. Keii, in: Proc. 7th Int. Congress in Catalysis, Tokyo, 1980 (Kodansha, Tokyo, 1980) 1414.

    Google Scholar 

  5. T. Baba, J. Sakai, H. Watanabe and Y. Ono, Bull. Chem. Soc. Jpn. 55 (1982) 2555.

    Google Scholar 

  6. C.M. Sorensen and R.S. Weber, in: Proc. 2nd China-U.S.-Japan Seminar on Heterogeneous Catalysis, Berkeley, 1985.

  7. W.E. Farneth, R.H. Staley, P.J. Domaille and R.D. Farlee, J. Am. Chem. Soc. 109 (1987) 4018.

    Google Scholar 

  8. J.G. Highfield and J.B. Moffat, J. Catal. 95 (1985) 108.

    Google Scholar 

  9. I.V. Kozhevnikov, Khimiya 12 (1985) 1.

    Google Scholar 

  10. G.A. Tsigdinos and C.J. Hallada, Inorg. Chem. 7 (1968) 137.

    Google Scholar 

  11. E.M. Serwicka, K. Bruckman, J. Haber, E.A. Paukshtis and E.N. Yurchenko, to be published.

  12. M.J.S. Dewar and W. Thiel, J. Am. Chem. Soc. 99 (1977) 4097 and 4899.

    Google Scholar 

  13. H. Taketa, S. Katsuki, K. Eguchi, T. Seiyama and N. Yamazoe, J. Phys. Chem. 90 (1986) 2959.

    Google Scholar 

  14. J.G. Highfield and J.B. Moffat, J. Catal. 95 (1985) 108.

    Google Scholar 

  15. E. Brocławik, unpublished data.

  16. R.I. Maksimovskaya, M.A. Fedotov, V.A. Mastikhin, L.I. Kuznetsova and K.I. Matveev, Dokl. Akad. Nauk SSSR 240 (1978) 117.

    Google Scholar 

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Authors and Affiliations

  1. Institute of Catalysis and Surface Chemistry, Polish Academy of Sciences, 30-239, Krakow, ul. Niezapominajek I, Poland

    E. M. Serwicka, E. Broclawik, K. Bruckman & J. Haber

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  1. E. M. Serwicka
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  2. E. Broclawik
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  3. K. Bruckman
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  4. J. Haber
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Serwicka, E.M., Broclawik, E., Bruckman, K. et al. TPD/TPR and quantum chemical study of methanol interaction with H3+n PV n Mo12-n O40 heteropolyacids. Catal Lett 2, 351–360 (1989). https://doi.org/10.1007/BF00768177

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  • DOI: https://doi.org/10.1007/BF00768177

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