Abstract
The crystal and molecular structure of bis(cyclopentadienyl)tungsten tetrasulphide, (C5H5)2WS4, has been determined from three-dimensional X-ray data collected by counter techniques. The coordination about the tungsten atom, consisting of the two terminal sulfur atoms of the tetrasulphide chain and the ring centroids of the two cyclopentadienyl rings, may be described as a distorted tetrahedron. The inner S-S bond distance is found to be somewhat shorter than the outer two S-S bond distances in the tetrasulphide chain. The substance crystallizes in the monoclinic space groupP21/n witha = 11·242(3),b = 12·154(5),c = 8·790(2) Å and β = 92·93(3) °. The structure was refined by least-squares techniques using 1581 independent reflections for whichFsk0/2 > 2σ(Fsk0/2), and the refinement converged at a conventionalR factor (onF) of 4·5 %.
Similar content being viewed by others
References
Abrahams, S. C. & Bernstein, J. L. (1969)Acta Crystallogr. B25, 2365.
Abrahams, S. C. & Grison, E. (1953)Acta Crystallogr. 6, 206.
Cameron, T. S., Prout, C. K., Rees, G. V., Green, M. L. H., Joshi, K. K., Davies, G. R., Kilbourn, B. T., Braterman, P. S. & Wilson, V. A. (1971)Chem. Commun., 14.
Corfield, P. W. R., Doedens, R. J. & Ibers, J. A. (1967)Inorg. Chem. 6, 197.
Cromer, D. T. (1970) to be published in the new edition of theInternational Tables for X-ray Crystallography, private communication.
Davis, B. R. & Bernal, I. (1971)J. Organomet. Chem. 30, 75.
Epstein, E. F. & Bernal, I. (1970)Chem. Commun., 410.
Epstein, E. F., Bernal, I., & Köpf, H. (1971)J. Organomet. Chem. 26, 229.
Foss, O. & Maroy, K. (1965)Acta Chemica Scand. 19, 2219.
Foss, O. (1960)Advances in Inorganic Chemistry and Radiochemistry, eds. Emeleus, H. J. & Sharpe, A. G. (Academic Press, New York, Vol. II, p. 237).
International Tables for X-ray Crystallography (1967) (The Kynoch Press, Birmingham, England).
Köpf, H. (1969a)Angew. Chem. internat. Edit. 8, 375.
Köpf, H. (1969b) private communication, Würzburg, Germany.
Ricci, Jr., J. S. & Bernal, I. (1971)J. Chem. Soc. [B], 1928.
Wheatley, P. J. (1967)Perspectives in Structural Chemistry, eds. Dunitz, J. D. & Ibers, J. A. (John Wiley and Sons, New York, p. 1).
Author information
Authors and Affiliations
Additional information
We wish to thank Dr. H. Köpf (Würzburg) for the gift of the crystals and the U.S. Atomic Energy Commission for financial support.
Rights and permissions
About this article
Cite this article
Davis, B.R., Bernal, I. Crystal and molecular structure of bis(cyclopentadienyl)tungsten tetrasulphide. Journal of Crystal and Molecular Structure 2, 135–142 (1972). https://doi.org/10.1007/BF01464794
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF01464794