Abstract
Measurements of physical properties were performed on the PrBa2Cu4O8-δ sample prepared by the sol-gel method and sintered in I atm oxygen pressure. Instead of exhibiting superconductivity as for R Y or Gd in the RBa2Cu4O8-δ compound. This compound is unstable, insulating but metallic-like at low temperatures. No superconductivity was observed down to 2 K. Since PrBa2Cu4O8-δ can be re-written as Cu2Ba2PrCu2O8-δ which is a compound of two CuO2-layers and two CuO-chains, the possibility of anomalous Pr antiferromagnetic ordering around 18 K observed from preliminary magnetic data and the effect of oxygen stoichiotmetry parameter δ on the metal-insulator transition are explored.
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Ku, H.C., You, Y.B., Sheen, S.R. et al. Magnetic and transport properties of PrBa2Cu4O8-δ prepared at 1 atm oxygen pressure. J Low Temp Phys 105, 1463–1468 (1996). https://doi.org/10.1007/BF00753906
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DOI: https://doi.org/10.1007/BF00753906