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Preparation and characterization of some metal(II) complexes of isocinchomeronic acid and X-ray crystal structure ofcis-diaquabis(hydrogen isocinchomeronato)manganese(II)

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Abstract

The reactions between Mn(II), Co(II), Ni(II), and Zn(II) ions with isocinchomeronic acid (H2-isocin) afforded complexes of the general formula M(H-isocin)2-2H2O, whereas Fe(II) gives both red and deep red-brown products of the same formula. Various physical measurements suggest that the complexes of M = Co, Ni, Zn, and Fe (brown) are octahedrally coordinated by two aqua ligands and twotrans-N,O-bidentate H-isocin− anions with dimeric hydrogen bonding. Those for M = Mn and Fe (red) are the correspondingcis isomers. The structure of the manganese complex as determined by X-ray crystallography exhibitsC 2 molecular symmetry with Mn-N = 2.279(2), Mn-O(H-isocin)− = 2.196(2), and Mn-O(aqua) = 2.137(2) Å. Each aqua ligand forms two donor O-H ⋯ O hydrogen bonds with carboxy groups of different molecules in adjacent chains.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Alexandria University, Alexandria, Egypt

    Mohamed A. S. Goher

  2. Department of Chemistry, The Chinese University of Hong Kong, Shatin, New Territories, Hong Kong

    Thomas C. W. Mak

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  1. Mohamed A. S. Goher
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Goher, M.A.S., Mak, T.C.W. Preparation and characterization of some metal(II) complexes of isocinchomeronic acid and X-ray crystal structure ofcis-diaquabis(hydrogen isocinchomeronato)manganese(II). Struct Chem 5, 165–170 (1994). https://doi.org/10.1007/BF02262837

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  • DOI: https://doi.org/10.1007/BF02262837

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