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Influence of the nature of the modifying cation on the activity and selectivity of CO/SiO2 catalysis of hydrocarbon synthesis from CO and H2

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Abstract

The catalytic properties of Co/SiO2 catalysis, modified with cations (L) of various chemical types, were investigated in the synthesis of higher hydrocarbons from synthesis gas. A number of changes ascertained in the specific catalytic activity and selectivity, depending on the nature of L, were interpreted on the basis of the previously substantiated mechanism of hydrogenation of CO on transition metals.

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Authors and Affiliations

  1. L. V. Pisarzhevskii Institute of Physical Chemistry, Ukrainian Academy of Sciences, Kiev

    N. V. Pavlenko, N. K. Lunev, V. L. Struzhko & E. I. Kosenko

Authors
  1. N. V. Pavlenko
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  2. N. K. Lunev
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  3. V. L. Struzhko
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  4. E. I. Kosenko
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Additional information

Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 28, No. 3, pp. 197–201, May-June, 1992.

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Pavlenko, N.V., Lunev, N.K., Struzhko, V.L. et al. Influence of the nature of the modifying cation on the activity and selectivity of CO/SiO2 catalysis of hydrocarbon synthesis from CO and H2 . Theor Exp Chem 28, 163–166 (1993). https://doi.org/10.1007/BF00529409

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  • DOI: https://doi.org/10.1007/BF00529409

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