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Strong metal-carrier interaction in cobalt- and nickel-titanium dioxide co-hydrogenation catalysts

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Abstract

X-ray photoelectron spectroscopy was used to show that in Co(Ni)-TiO2 catalysts (rutile, anatase) the phenomenon of strong metal-carrier interaction consists of electron interplay between the metal and the carrier (rutile) and partial migration of the oxide onto the metal. This effect was more clearly seen in the rutile samples and accounts for their greater activity and selectivity towards the higher hydrocarbons in CO hydrogenation.

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Authors and Affiliations

  1. L. V. Pisarzhevskii Institute of Physical Chemistry, Ukrainian Academy of Sciences, Kiev

    I. T. Chashechnikova, V. M. Vorotyntsev, V. V. Borovik, G. I. Golodets, I. V. Plyuto & A. P. Shpak

Authors
  1. I. T. Chashechnikova
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  2. V. M. Vorotyntsev
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  3. V. V. Borovik
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  4. G. I. Golodets
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  5. I. V. Plyuto
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  6. A. P. Shpak
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Additional information

Deceased.

Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 28, No. 3, pp. 216–219, May–June, 1992.

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Chashechnikova, I.T., Vorotyntsev, V.M., Borovik, V.V. et al. Strong metal-carrier interaction in cobalt- and nickel-titanium dioxide co-hydrogenation catalysts. Theor Exp Chem 28, 176–178 (1993). https://doi.org/10.1007/BF00529413

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  • DOI: https://doi.org/10.1007/BF00529413

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