Abstract
Solid oxides selective in mild oxidation exhibit a definite crystal morphology. Each crystal face displays a surface crystal field which rules the transformation of the reactant to a given product. The catalytic metastability of the surface which has to be maintained in the operating conditions prevailing in reactors depends on the reactivity of the bulk, because of oxygen diffusion process. Application to VPO, the catalyst for oxidation of n-butane to maleic anhydride, gives the opportunity to examine these properties in the series preparation–activation–catalysis–ageing, in relation to the type of catalytic reactor.
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References
J. Haber, Int. Chem. Eng. 15 (1975) 21.
J. Haber, Pure Appl. Chem. 50 (1978) 923; 56 (1984) 1663.
A. Bielanski and J. Haber, Catal. Rev. Sci. Eng. 19 (1979) 1.
J. Haber, in: Solid State Chemistry in Catalysis, ACS Symp. Series, Vol. 279, eds. R.K. Grasselli and J.F. Brazdil (Am. Chem. Soc., Washington, DC, 1985) p. 3.
J. Haber, in: Structure and Reactivity of Surfaces, Stud. Surf. Sci. Catal., Vol. 48, eds. C. Marterra, A. Zecchina and G. Costa (Elsevier, Amsterdam, 1989) p. 447.
J. Haber, in: Perspectives in Catalysis, eds. J.M. Thomas and K.I. Zamaraev.
E. Bordes and P. Courtine, J. Catal. 57 (1979) 236.
B.K. Hodnett, Catal. Rev. Sci. Eng. 27 (1985) 373.
B.K. Hodnett, ed., Selective Catalytic Oxidation of C 4 Hydrocarbons to Maleic Anhydride, Catal. Today 1 (1987).
G. Centi and F. Trifirò, Chem. Rev. 88 (1988) 55.
E. Bordes, Catal. Today 1 (1987) 499; 3 (1988) 163; 16 (1993) 27.
G. Centi, ed., Vanadyl Pyrophosphate Catalysts, Catal. Today 16 (1993).
R.M. Contractor, D.I. Garnett, H.S. Horowitz, H.E. Bergna, G.S. Patience, J.T. Schwartz and G.M. Sisler, Stud. Surf. Sci. Catal. 82 (1994) 233.
E. Bordes and R.M. Contractor, Topics Catal. 3 (1996) 365.
E. Bordes, in: Elementary Reaction Steps in Heterogeneous Catalysis, eds. R.W. Joyner and R.A. van Santen (Kluwer Academic, Amsterdam, 1993) pp. 137–153.
P. Courtine, in: Solid State Chemistry in Catalysis, ACS Symp. Series, Vol. 279, eds. R.K. Grasselli and J.F. Brazdil (Am. Chem. Soc., Washington, DC, 1985) p. 37.
J.-C. Volta and J.-L. Portefaix, Appl. Catal. 18 (1985) 1.
P.J. Gellings and H.J.M. Bouwmeester, Catal. Today 12 (1992).
R.K. Grasselli, J.D. Burrington and J.F. Brazdil, J. Chem. Soc., Faraday Disc. 72 (1982) 203.
J. Mars and D.W. van Krevelen, Special Suppl., Chem. Eng. Sci. 3 (1954) 41.
A. Lebouteiller and P. Courtine, J. Solid State Chem. 137 (1998) 94.
J.A. Duffy, Geochim. Cosmochim. Acta 57 (1993) 3961.
A. Lebouteiller, P. Moriceau, E. Bordes and P. Courtine, in: Proc. DGMK Conf. Selective Oxidations in Petrochemistry, Tagungsbericht 9803, eds. G. Emig, C. Kohlpainter and B. Lücke, Hambourg, 8–9 October 1998, p. 95.
A. Lebouteiller, P. Moriceau, E. Bordes and P. Courtine, Phys. Chem. Chem. Phys. 1 (1999) 5735.
E. Bordes, in: Structure-Activity and Selectivity Relationships in Heterogeneous Catalysis, Stud. Surf. Sci. Catal., Vol. 67, eds. R.K. Grasselli and A.W. Sleight (Elsevier, Amsterdam, 1991) p. 21.
A. Véjux and P. Courtine, J. Solid. State Chem. 23 (1978) 93; 63 (1986) 179.
P. Courtine and E. Bordes, Appl. Catal. A 157 (1997) 45.
P. Courtine and E. Bordes, in: Proc. 3rd World Congr. Oxidation Catalysis, Stud. Surf. Sci. Catal., Vol. 110, eds. R.K. Grasselli, S.T. Oyama, A.M. Gaffney and J.E. Lyons (Elsevier, Amsterdam, 1997) 177.
B. Adamska, K. Brückman and B. Grzybowska, Bull. Acad. Polon. Sci., Ser. Sci. Chim. 26 (1978) 159.
B. Grzybowska, Appl. Catal. A 157 (1997) 263.
J. Védrine, ed., Eurocat Oxides, Catal. Today 20 (1994).
N. Duvauchelle, E. Kesteman, F. Oudet and E. Bordes, J. Solid State Chem. 137 (1998) 311.
F.S. Stone, J. Solid. State Chem. 12 (1975) 271.
J. Ziolkowski, J. Catal. 100 (1990) 45.
J. Ziolkowski, E. Bordes and P. Courtine, J. Catal. 122 (1990) 126.
J. Ziolkowski and E. Bordes, J. Mol. Catal. 84 (1993) 307.
J. Haber and M. Witko, 14th North-American Meet. Catal. Society, Snowbird, 12–16 June 1995.
P.L. Gai-Boyes, Acta Cryst. B 53 (1997) 346.
N. Duvauchelle and E. Bordes, Catal. Lett. 57 (1999) 81.
E. Bordes, J.W. Johnson, A. Raminosona and P. Courtine, Mater. Sci. Monograph. 28B (1985) 887.
F.B. Abdelouahab, R. Olier, N. Guilhaume, F. Lefebvre and J.C. Volta, J. Catal. 134 (1992) 151.
R.M. Contractor et al., US Patent 4,668,802 (26 May 1987), E. I. DuPont de Nemours.
R.M. Contractor, H.E. Bergna, H.S. Horowitz, C.M. Blackstone, U. Chowdry and A.W. Sleight, in: Catalysis, ed. J.W. Ward (1987) p. 645.
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Bordes, E., Courtine, P. Influence of structural properties of catalysts at various stages of selective oxidation: from catalyst preparation to catalytic reactors. Topics in Catalysis 11, 61–65 (2000). https://doi.org/10.1023/A:1027238217490
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DOI: https://doi.org/10.1023/A:1027238217490