Skip to main content
Log in

Recombination of preadsorbed oxygen atoms at the surface of solids

  • Published:
Technical Physics Letters Aims and scope Submit manuscript

Abstract

Relaxation measurements are used to establish that for a concentration of gas-phase oxygen atoms n=1014 cm−3 heterogeneous recombination of oxygen atoms at the surface of copper and zinc sulfide takes place by a mechanism involving recombination of preadsorbed (precursor state) atoms. A hypothesis is put forward for the existence of a universal mechanism for the catalytic acceleration of heterogeneous chemical reactions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. V. F. Kharlamov, Poverkhnost’ No. 11, 122 (1993).

  2. V. F. Kharlamov, Recombination of Atoms at the Surface of Solids and Accompanying Effects [in Russian], Tomsk State University Press, Tomsk (1994), 207 pp.

    Google Scholar 

  3. V. F. Kharlamov, Sh. L. Izmailov, and N. Ph. Vasil’ev, React. Kinet. Catal. Lett. 60(1), 107 (1997).

    Google Scholar 

  4. Sh. L. Izmailov and V. F. Kharlamov, Kinet. Katal. 23, 1183 (1982).

    Google Scholar 

  5. V. F. Kharlamov, K. M. Anufriev, Yu. V. Mosin et al., Pis’ma Zh. Tekh. Fiz. 24(5), 23 (1998) [Tech. Phys. Lett. 24, 176 (1998)].

    Google Scholar 

  6. V. F. Kharlamov, V. N. Lisetskii, and O. A. Ivashchuk, Zh. Fiz. Khim. 72(2), 297 (1997).

    Google Scholar 

  7. V. F. Kharlamov, N. F. Vasil’ev, O. A. Ivashchuk et al., Pis’ma Zh. Tekh. Fiz. 24(3), 54 (1998) Tech. Phys. Lett. 24, 105 (1998)].

    Google Scholar 

  8. M. W. Roberts and C. S. McKee, Chemistry of the Metal-Gas Interface (Clarendon Press, Oxford, 1978; Mir, Moscow, 1981, p. 317).

    Google Scholar 

  9. O. V. Krylov and B. R. Shub, Nonequilibrium Processes in Catalysis [in Russian], Moscow (1990), 288 pp.

Download references

Author information

Authors and Affiliations

Authors

Additional information

Pis’ma Zh. Tekh. Fiz. 25, 27–32 (August 12, 1999)

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kharlamov, V.F., Anufriev, K.M. Recombination of preadsorbed oxygen atoms at the surface of solids. Tech. Phys. Lett. 25, 603–605 (1999). https://doi.org/10.1134/1.1262570

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1134/1.1262570

Keywords

Navigation