Abstract
Using a relativistic molecular DFS code we have calculated a self-consistent many electron relativistic correlation diagram of the system Cl-Ar. The resulting energy for the 2pπ-1sσ transition is in complete agreement with the experimental results of Schuch et al./1/. This definitely confirms their claim that they are able to measure this quantity from interference structures observed in quasi-molecular K-X-ray spectra.
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Supported by Gesellschaft für Schwerionenforschung, Darmstadt.
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Fricke, B., Sepp, W.D. & Morović, T. Ab initio many electron relativistic molecular DFS-calculations of inner shell MO-transitions. Z Physik A 318, 369–370 (1984). https://doi.org/10.1007/BF01418097
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DOI: https://doi.org/10.1007/BF01418097