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Synthesis and NMR characterization of new poly(ethoxyalkyl) maleates

Surfactants for emulsion polymerization

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Summary

Polymerizable surfactants derived from maleic anhydride have been synthesized. The hydrophilic part is obtained by a controlled ethylene oxide polymerization according to a new heterogeneous catalytic process. Some maleates derivatives have been obtained and fully characterized by 1H and 13C NMR. Their cmc were also measured. Some of them have been engaged in styrene emulsion polymerization in which monodisperse latex particles have been produced.

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Authors and Affiliations

  1. Laboratoire de Chimie et Procédés de Polymérisation, C.N.R.S., BP 24, F-69390, Vernaison, France

    T. Hamaide, C. Monnet & A. Guyot

  2. Faculty of Chemistry, University of Latvia, 19, Boulevard Rainis, LV-1098, Riga, Lativa

    A. Zicmanis

Authors
  1. T. Hamaide
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  2. A. Zicmanis
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  3. C. Monnet
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  4. A. Guyot
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Hamaide, T., Zicmanis, A., Monnet, C. et al. Synthesis and NMR characterization of new poly(ethoxyalkyl) maleates. Polymer Bulletin 33, 133–139 (1994). https://doi.org/10.1007/BF00297347

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  • DOI: https://doi.org/10.1007/BF00297347

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