Abstract
The structural relaxation and crystallization processes of the Cu50Zr50 amorphous alloy have been studied by field ion microscopy (FIM) on an atomic scale. An interesting phenomenon which we call the clustering effect was observed for the first time as far as we know. In the temperature range 673–723 K, clusters consisting of 3, 4, or 5 atoms formed and migrated towards certain crystalline centers. They then combined with one another and rearranged to produce an ordered atomic array. This clustering process including the formation, migration, combination and rearrangement of clusters is considered as a structural relaxation process.
Similar content being viewed by others
References
U. Koster, U. Herold: In Glassy Metals I, ed. by H.J. Guntherrodt, H. Beck, Topics Appl. Phys. 46, (Springer, Berlin, Heidelberg 1981) p. 225
E.W. Muller, T.T. Tsong: Field Ion Microscopy, Principles and Applications (Elsevier, New York 1969)
A. Revcolevschi, N.J. Grant: Metall. Trans. 3, 1545 (1972)
T. Masumoto, R. Maddin: Mater. Sci. Eng. 19, 1 (1975)
D.J. Smith, W.M. Stobbs, W.O. Saxton: Philos. Mag. B43, 907 (1981)
T. Imura, M. Doi, M. Makiyama, Y. Itoh: In Rapidly Quenched Metals IV, ed. by T. Masumoto, K. Suzuki (The Japan Institute of Metals, Sendai 1982) Vol. 1, p. 605
Y. Ishida, H. Ichinose, H. Shimada, H. Kojima: In Rapidly Quenched Metals IV, ed. by T. Masumoto, K. Suzuki (The Japan Institute of Metals, Sendai 1982) Vol. 1, p. 421
J.D. Bernal: Nature 183, 141 (1959); 185, 68 (1960)
T. Hamada, F.E. Fujita: Jpn. J. Appl. Phys. 21, 981 (1982)
T. Hamada, F.E. Fujita: Jpn. J. Appl. Phys. 24, 249 (1985)
C.S. Hsu, A. Rahman: J. Chem. Phys. 70, 5234 (1979)
F.E. Fujita: Proc. 4th Int. Conf. Rapidly Quenched Metals, Sendai, Japan, 1981
E. Kneller, Y. Khan, U. Gorres: Z. Metallk. 77, 43 (1986); 77, 152 (1986)