Skip to main content
Log in

Structural changes in excited states and photoisomers determined by time-resolved Raman scattering

  • Time-Resolved Vibrational Spectroscopy
  • Published:
Applied Physics B Aims and scope Submit manuscript

Abstract

Molecules in the excited singlet and triplet state and photoproducts occuring after photoisomerization or proton transfer are investigated by time-resolved resonance Raman and resonance CARS spectroscopy with nanosecond time resolution. From the time-resolved spectra information on structures and bond strengths of these short-lived species and on their kinetics are obtained.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. G.H. Atkinson: InAdvances in Laser Spectroscopy, ed. by B.A. Garetz, J.R. Lombardi, Vol. 1. (Heyden, London 1982)

    Google Scholar 

  2. G.H. Atkinson: InAdvances in Infrared and Raman Spectroscopy ed. by R.J.H. Clark, R.E. Hester, Vol. 9. (Heyden, London 1982)

    Google Scholar 

  3. J. Terner, M.A. El-Sayed: Acc. Chem. Res.18, 331 (1985)

    Google Scholar 

  4. S. Maeda, T. Kamisuki, H. Kataoka, Y. Adachi: Appl. Spectrosc. Rev.21, 211 (1985)

    Google Scholar 

  5. H. Hamaguchi: InVibrational Spectra and Structure, ed. by J.R. Durig, Vol. 16. (Elsevier, Amsterdam 1987)

    Google Scholar 

  6. A.H. Atkinson (ed.):Time-Resolved Vibrational Spectroscopy, (Academic, New York 1983)

    Google Scholar 

  7. A. Laubereau, M. Stockburger (eds.):Time-Resolved Vibrational Spectroscopy, Springer Proc. Phys., Vol. 4 (Springer, Berlin, Heidelberg 1985)

    Google Scholar 

  8. H. Takahashi (ed.):Time-Resolved Vibrational Spectroscopy V, Springer Proc. Phys., Vol. 68 (Springer, Berlin, Heidelberg 1991)

    Google Scholar 

  9. M. Stockburger, T. Alshuth, D. Oesterhelt, W. Gärtner: InSpectroscopy of Biological Systems, ed. by R.J.H. Clark, R.E. Hester (Wiley, New York 1986)

    Google Scholar 

  10. Y. Koyama, Y. Mukai: InBiomolecular Spectroscopy, Part B, ed. by R.J.H. Clark, R.E. Hester (Wiley, New York 1993)

    Google Scholar 

  11. K. Iwata, H. Hamagushi: InTime-Resolved Vibrational Spectroscopy VI, ed. by A. Lau, F. Siebert, W. Werncke, Springer Proc. Phys., Vol. 74 (Springer, Berlin, Heidelberg 1994) p. 85 J.N. Moore, P. Matousek, A.W. Parker, W.T. Toner, M. Towrie, R.E. Hester: InTime-Resolved Vibrational Spectroscopy VI, ed. by A. Lau, F. Siebert, W. Werncke, Springer Proc. Phys., Vol. 74 (Springer, Berlin, Heidelberg 1994) p. 89 D.L. Phillips, J.-M. Rodier, A.B. Myers: InTime-Resolved Vibrational Spectroscopy VI, ed. by A. Lau, F. Siebert, W. Werncke, Springer Proc. Phys., Vol. 74 (Springer, Berlin, Heidelberg 1994) p. 95

    Google Scholar 

  12. A. Lau, W. Werncke, M. Pfeiffer: Spectrochim. Acta Rev.13, 191 (1990)

    Google Scholar 

  13. V.F. Kamalov, N.I. Koroteev, B.N. Toleutaev: InTime Resolved Spectroscopy, ed. by R.J.H. Clark, R.E. Hester, Vol. 18, (Wiley, Chichester 1989) p. 255

    Google Scholar 

  14. T. Tahara, H. Hamaguchi, M. Tasumi: J. Phys. Chem.91, 5875 (1987); Chem. Phys. Lett.152, 135 (1988)

    Google Scholar 

  15. A. Mavridis, I. Moustakali-Mavridis: Acta Cryst. B33, 3612 (1977)

    Google Scholar 

  16. T. Hoshi, K. Ota, J. Yoshino, K. Murofushi, Y. Tanizaki: Chem. Lett.4, 357 (1977)

    Google Scholar 

  17. H. Hiura, H. Takahashi: J. Phys. Chem.96, 1909 (1992)

    Google Scholar 

  18. E.B. Wilson, Jr.: Phys. Rev.45, 706 (1934)

    Google Scholar 

  19. H. Isaka, J. Abe, T. Ohzeki, Y. Sakaino, H. Takahashi: J. Mol. Struct.178, 101 (1988)

    Google Scholar 

  20. J. Abe, T. Miyazaki, H. Takahashi: J. Chem. Phys.90, 2317 (1989)

    Google Scholar 

  21. H.-J. Weigmann, K. Lenz, J. Pätzold, M. Pfeiffer, W. Werncke: Chem. Phys. Lett.61, 105 (1979) H.-J. Weigmann, K. Lenz, A. Lau, M. Pfeiffer, W. Werncke: Chem. Phys. Lett.73, 1 (1980)

    Google Scholar 

  22. C.H. Jung, A. Lau, H.-J. Weigmann, W. Werncke, M. Pfeiffer: Chem. Phys.72, 327 (1982)

    Google Scholar 

  23. N.I. Koroteev, A.P. Shkurinov, B.N. Toleutaev: InCoherent Raman Spectroscopy, ed. by G. Marowsky, V.V. Smirnov, Springer Proc. Phys., Vol. 63 (Springer, Berlin, Heidelberg 1992) p. 186

    Google Scholar 

  24. H. Hayashi, S.V. Kolaczkowski, T. Noguchi, D. Blanchard, G.R. Atkinson: J. Am. Chem. Soc.112, 4664 (1990)

    Google Scholar 

  25. G. Scheibe, J. Heiss, K. Feldmann: Ber. Bunsenges. Phys. Chem.70, 52 (1966)

    Google Scholar 

  26. H. Hartmann, P. Wähner: Abstracts Fourth Symposium Optical Spectroscopy, Reinhardsbrunn, GDR (1986) Paper SOS-P 59

    Google Scholar 

  27. M. Pfeiffer, W. Werncke, A. Lau, W. Freyer: InElectronic Properties of Polymers, ed. by H. Kuzmany, M. Mehring, S. Roth, Springer Ser. Solid-State Sci., Vol. 107 (Springer, Berlin, Heidelberg 1991)

    Google Scholar 

  28. W. Werncke, M. Pfeiffer, A. Lau, L. Holz, T. Hasche: Inst. Phys. Conf. Ser.126, 557 (1992)

    Google Scholar 

  29. W. Werncke, A. Lau, M. Pfeiffer, H.-J. Weigmann, W. Freyer, T.J. Tscholl, K.M. Bok: Chem. Phys.118, 133 (1987)

    Google Scholar 

  30. H. Takahashi, S. Hirukawa, S. Suzuki, Y. Torii, H. Isaka: J. Mol. Struct.146, 91 (1986)

    Google Scholar 

  31. S. Suzuki, H. Isaka, S. Ito, S. Hirukawa, S. Matsubara, H. Takahashi: J. Raman Spectrosc.18, 105 (1987)

    Google Scholar 

  32. H. Kimura, H. Takahashi: J. Mol. Struct.293, 1 (1993)

    Google Scholar 

  33. N.C. Yang, C. Rivas: J. Am. Chem. Soc.83, 2213 (1961)

    Google Scholar 

  34. R.C. Bertelson: InPhotochromism, ed. by G.H. Brown (Wiley-Interscience, New York: 1971) and references therein

    Google Scholar 

  35. H. Takahashi, K. Yoda, H. Isaka, T. Ohzeki, Y. Sakaino: Chem. Phys. Lett.140, 90 (1987)

    Google Scholar 

  36. K. Uji, K. Kikuchi, -H. Kokubun: J. Photochem.10, 145 (1979)

    Google Scholar 

  37. T. Nakayama, K. Hananoue, T. Hidaka, M. Okamoto, H. Teranishi: J. Photochem.24, 71 (1984)

    Google Scholar 

  38. T. Ohzeki, H. Ohgusa, H. Isaka, S. Suzuki, H. Takahshi: Chem. Phys. Lett.149, 379 (1988)

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Takahashi, H., Werncke, W., Pfeiffer, M. et al. Structural changes in excited states and photoisomers determined by time-resolved Raman scattering. Appl. Phys. B 59, 403–414 (1994). https://doi.org/10.1007/BF01081063

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01081063

PACS

Navigation