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Ramanspektroskopische Untersuchungen an festem Vanadiumoxidtrichlorid VOCl3

Raman spectrum of solid VOCl3

  • Anorganische, Struktur- und Physikalische Chemie
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Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Abstract

A high resolution Raman spectrum of polycrystalline VOCl3 at −196 °C has been recorded. Besides the chlorine isotope splitting a further splitting of 3 of the 6 fundamentals has been observed. The number of the Raman lines in the ν4 and ν6 region and the intensity ratios in the ν2 region will be explained by a factor group splitting of 2 VOCl3 molecules in the unit cell.

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Authors and Affiliations

  1. Anorganisch-Chemisches Institut, Technische Universität Clausthal, D-3392, Clausthal-Zellerfeld, Bundesrepublik Deutschland

    A. Feza Demiray &  Wolfgang Brockner

Authors
  1. A. Feza Demiray
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  2. Wolfgang Brockner
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Demiray, A.F., Brockner, W. Ramanspektroskopische Untersuchungen an festem Vanadiumoxidtrichlorid VOCl3 . Monatshefte für Chemie 107, 433–437 (1976). https://doi.org/10.1007/BF00906872

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  • DOI: https://doi.org/10.1007/BF00906872

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