Abstract
TheRaman spectra of solid and molten SeOBr2 as well as of a CCl4 solution have been recorded for the first time. The spectra indicate associated molecules in the molten state and relatively strong intermolecular interactions in the solid. Monomeric pyramidal molecules are present in the CCl4 solution. An assignment will be discussed in analogy to SeOCl2.
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W. Bues, W. Brockner undF. Demiray, Spectrochim. Acta30 A, 579 (1974).
W. Brockner, H. Hovdan undS. J. Cyvin, Z. Naturforsch.29 a, 620 (1974).
A. F. Demiray undW. Brockner, Mh. Chem.107, 433 (1976).
W. Bues, W. Brockner undF. Demiray, Z. anorg. allg. Chem.434, 249 (1977).
J. C. Sheldon undS. Y. Tyree, Jr., J. Amer. Chem. Soc.81, 2290 (1959).
Y. Hermodsson, Acta Chem. Scand.21, 1313 (1967).
D'Ans-Lax, Taschenbuch für Chemiker und Physiker, Band I, S. 1–530. Berlin-Heidelberg-New York: Springer. 1967.
Gmelins Handbuch, Selen B, S. 153ff. Clausthal-Zellerfeld: Gmelin-Verlag. 1949.
V. Lehner, J. Amer. Chem. Soc.44, 1668 (1922).
W. Bues, W. Brockner undD. Grünewald, Spectrochim. Acta28 A, 1519 (1972).
H. A. Øye undW. Bues, Inorg. Nucl. Chem. Letters8, 31 (1972).
L. E. Alexander undI. R. Beattie, J. Chem. Soc. Dalton Trans.1972, 1745.
H. Gerding, E. Smit undR. Westrik, Rec. Trav. Chim. Pays-Bas60, 513 (1941).
R. Paetzold, Z. Chem.4, 272 (1964).
R. A. Suthers undT. Henshall, Z. anorg. allg. Chem.388, 269 (1972).
J. C. Dewan undA. J. Edwards, J. Chem. Soc. Dalton Trans.1976, 2433.
Y. Hermodsson, Ark. Kemi31, 199 (1969).
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Brockner, W., Demiray, A.F. Ramanspektroskopische Untersuchungen an Seleninyldibromid. Monatshefte für Chemie 110, 525–529 (1979). https://doi.org/10.1007/BF00938357
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DOI: https://doi.org/10.1007/BF00938357