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Stabilitäten von As(V) in Chlorokomplexen

Stability of As(V) in chlorocompounds

  • Anorganische, Struktur- und Physikalische Chemie
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Monatshefte für Chemie - Chemical Monthly Aims and scope Submit manuscript

Abstract

The temperature dependent behaviour of PCl4AsCl6, PCl4SbCl6 and AsCl4SbCl6 has been investigated byRaman spectroscopy. The As(V) containing complexes decompose into homogeneous molecular melts consisting of AsCl3, Cl2 and PCl5, respectively. In PCl4SbCl6 PCl4 + and SbCl6 − complex ions were found in the solid as well as in the molten state.

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Literatur

  1. L. Kolditz, Advances7, 1 (1965).

    CAS  Google Scholar 

  2. H. M. Powell, D. Clark undA. F. Wells, J. Chem. Soc.1942, 642.

  3. P. v. Huong undB. Desbat, Bull. Soc. Chim. France7, 2631 (1972).

    Google Scholar 

  4. K. Seppelt, Angew. Chem.88, 410 (1976).

    Article  CAS  Google Scholar 

  5. K. Seppelt, Z. anorg. allg. Chem.434, 5 (1977).

    Article  CAS  Google Scholar 

  6. S. M. Ohlberg, J. Amer. Chem. Soc.81, 811 (1959).

    Article  CAS  Google Scholar 

  7. H. Chihara, N. Nakamura, H. Okuma undS. Seki, Bull. Chem. Soc. Jap.41, 1809 (1968).

    Article  CAS  Google Scholar 

  8. K. Olie, C. C. Smitskamp undH. Gerding, Inorg. Nucl. Chem. Letters4, 129 (1968).

    Article  CAS  Google Scholar 

  9. W. Bues, F. Demiray undW. Brockner, Spectrochim. Acta30A, 1709 (1974).

    Article  CAS  Google Scholar 

  10. R. Heimburger undM. J. F. Leroy, Spectrochim. Acta31A, 635 (1975).

    Google Scholar 

  11. W. Brockner, S. J. Cyvin undH. Hovdan, Inorg. Nucl. Chem. Letters11, 171 (1975).

    Article  CAS  Google Scholar 

  12. W. Bues, F. Demiray undW. Brockner, Raman Newsletter78, 6 (1975).

    Google Scholar 

  13. W. Bues, W. Brockner undD. Grünewald, Spectrochim. Acta28A, 1519 (1972).

    Article  Google Scholar 

  14. H. A. Øye undW. Bues, Inorg. Nucl. Chem. Letters8, 31 (1972).

    Article  Google Scholar 

  15. P. W. Davis undR. A. Oetjen, J. Mol. Spectr.2, 253 (1958).

    Article  CAS  Google Scholar 

  16. H. Siebert, Anwendungen der Schwingungsspektroskopie in der anorganischen Chemie. Berlin-Heidelberg-New York: Springer. 1966.

    Book  Google Scholar 

  17. F. J. Brinkmann, H. Gerding undK. Olie, Rec. Trav. Chim.88, 1359 (1969).

    Google Scholar 

  18. P. Reich undH. Preiss, Z. Chem.7, 115 (1967).

    Article  CAS  Google Scholar 

  19. I. R. Beattie, T. Gilson, K. Livingston, V. Fawcett undG. A. Ozin, J. Chem. Soc. (A)1967, 712.

  20. F. W. Poulsen, 7th Euchem Conference on Molten Salts, Lysekil, Schweden, 1978.

  21. G. Okon, Dissertation, Technische Universität Clausthal, 1976.

  22. W. Brockner undA. F. Demiray, eingereicht an Z. Naturf.

  23. A. F. Demiray undW. Brockner, Spectrochim. Acta, im Druck.

  24. A. F. Demiray undW. Brockner, Mh. Chem., im Druck.

  25. L. Kolditz undW. Schmidt, Z. anorg. allg. Chem.296, 188 (1958).

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Anorganisch-Chemisches Institut, Technische Universität Clausthal, D-3392, Clausthal-Zellerfeld, Germany

    A. Feza Demiray & Wolfgang Brockner

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  1. A. Feza Demiray
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  2. Wolfgang Brockner
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Demiray, A.F., Brockner, W. Stabilitäten von As(V) in Chlorokomplexen. Monatshefte für Chemie 110, 799–804 (1979). https://doi.org/10.1007/BF00906673

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