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Ramanspektroskopische Untersuchungen an PCl5 II. Das System PCl5—ZrCl4

Raman spectra of the system PCl5—ZrCl4

  • Inorganic, Structural, and Physical Chemistry
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Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Abstract

Raman spectra of some solid and molten PCl5−ZrCl4 mixtures have been recorded. ZrCl6 2− complex ions accompanied by at least one more chlorozirconate species are present in the solid as well as in the melt. The newRaman frequencies are attributed to ZrCl5 −, which fundamentals are given and assignment is proposed to be analogous to TiCl5 −. The presence of ZrCl6 2− and ZrCl5 − can be explained by the equilibrium ZrCl6 2−+PCl4 +⇌ZrCl5 −+PCl5.

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Authors and Affiliations

  1. Anorganisch-Chemisches Institut, Technische Universität Clausthal, D-3392, Clausthal-Zellerfeld, Bundesrepublik Deutschland

    A. Fezâ Demiray & Wolfgang Brockner

Authors
  1. A. Fezâ Demiray
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  2. Wolfgang Brockner
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Demiray, A.F., Brockner, W. Ramanspektroskopische Untersuchungen an PCl5 II. Das System PCl5—ZrCl4 . Monatshefte für Chemie 111, 21–27 (1980). https://doi.org/10.1007/BF00938713

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  • DOI: https://doi.org/10.1007/BF00938713

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