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Beiträge zur Chemie der Silicium-Stickstoff-Verbindungen, 166. Mitt.: Organylaminosubstitutionen an Hexachlordisiloxan

Chemistry of silicon-nitrogen compounds, CLXVI: Organylamino substitutions on hexachlorodisiloxane

  • Anorganische Und Physikalische Chemie
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Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Summary

Reaction of hexachlorodisiloxane with primary and secondary amines leads — in dependence of stoichiometry — to numerous partially and totally organylamino substituted disiloxanes. Partially aminosubstituted chlorodisiloxanes are very sensitive to moisture and can be converted into disiloxanes with different organylamino groups. Exhaustive alkanolysis substitutes amino as well as chloro groups giving hexaalkoxydisiloxanes, but partial alkanolysis may substitute amino in preference to chloro groups. Mass spectra can be interpreted by abstraction ofRR′N·,RR′N+,RR′NH and (RR′N minus H) units. Most of the compounds are colourless liquids but hexakis(piperidino)-disiloxane melts at 270 °C.

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Authors and Affiliations

  1. Institut für Anorganische und Analytische Chemie, Technische Universität Braunschweig, D-W-3300, Braunschweig, Bundesrepublik Deutschland

    Ulrich Wannagat, Gabriele Bogedain, Hamid Hajibegli & Hans-Heinrich Moretto

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  1. Ulrich Wannagat
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  2. Gabriele Bogedain
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  3. Hamid Hajibegli
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  4. Hans-Heinrich Moretto
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Gewidmet Herrn Prof. Dr. Edwin Hengge zum 60. Geburtstag

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Wannagat, U., Bogedain, G., Hajibegli, H. et al. Beiträge zur Chemie der Silicium-Stickstoff-Verbindungen, 166. Mitt.: Organylaminosubstitutionen an Hexachlordisiloxan. Monatsh Chem 121, 865–874 (1990). https://doi.org/10.1007/BF00808949

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  • DOI: https://doi.org/10.1007/BF00808949

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