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Darstellung und Eigenschaften von Heteropolykationenverbindungen, IV: Darstellung und Struktur von Natriumdodekaaluminogalliumsulfat-Ikosihydrat, Na[GaO4Al12(OH)24(H2O)12](SO4)4 ·xH2O mitx∼20

Synthesis and properties of heteropolycation compounds, IV. Synthesis and structure of sodium-dodecaalumino-galliumsulfate-ikosihydrate, Na[GaO4Al12(OH)24(H2O)12](SO4)4 ·xH2O (x∼20)

  • Anorganische Und Physikalische Chemie
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Summary

A chemical analyses of Na[GaO4(Al12(OH)24(H2O)12](SO4)4 ·xH2O withx∼20 [a=17.861 (4) Å; F\(\bar 4\)3 m-T 2d ;Z=4] in connection with a crystal structure investigation confirmed the tetrahedral coordination of the gallium atom by oxygen atoms, as well as the far extending statistical distribution of the crystal water in the structure. The syntheses was done by neutralization of a satured aqueous aluminium chloride solution, mixed with metallic gallium and sodium sulfate, by an aqueous sodiumhydroxide solution.

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Authors and Affiliations

  1. Fachbereich Chemie, WB „Anorganische Chemie“, Bergakademie Freiberg, D-O-9200, Freiberg, Bundesrepublik Deutschland

    Hedda Görz & Siegfried Schönherr

  2. Institut für Mineralogie und Kristallographie, Universität Wien, A-1010, Wien, Österreich

    Franz Pertlik

Authors
  1. Hedda Görz
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  2. Siegfried Schönherr
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  3. Franz Pertlik
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Görz, H., Schönherr, S. & Pertlik, F. Darstellung und Eigenschaften von Heteropolykationenverbindungen, IV: Darstellung und Struktur von Natriumdodekaaluminogalliumsulfat-Ikosihydrat, Na[GaO4Al12(OH)24(H2O)12](SO4)4 ·xH2O mitx∼20. Monatsh Chem 122, 759–764 (1991). https://doi.org/10.1007/BF00815915

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  • DOI: https://doi.org/10.1007/BF00815915

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