Abstract
Light scattering measurement was carried out for aqueous solutions of amphiphilic molecules mixed with aromatic unsaturated carboxylic acids. Their structures are discussed according to sizes of molecular assemblies evaluated. In aqueous solutions of hexadecyltrimethylammonium hydroxide with 2-indenecarboxylic acid, short rodlike micelles were formed on mixing at a ratio of 1∶1. Particles in aqueous solutions of dodecyldimethylamine oxide and cinnamic acid varied from micelles to vesicles with increasing cinnamic acid concentration. The structures were related to the effective photocyclodimerization of olefins and the stereochemical selectivity of cyclodimers.
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References
Thomas JK (1984) The Chemistry of Excitation at Interfaces; ACS Monograph 181: American Chemical Society: Washington D C
Fox MA (1985) Organic Phototransformations in Non-homogeneous Media; American Chemical Society: Washington DC
Ramamurthy V (1986) Tetrahedron 42:5753
Kalyanasundaram K (1987) Photochemistry in Microheterogeneous Systems; Academic Press Inc: Orland Florida
Takagi K, Sawaki Y (1993) Critical Rev Biochem Mol Biol 28:323
Cohen MD (1975) Angew Chem Int Ed Engl 14:386
Quina FH, Mobius D, Carroll FA, Hopf FR, Whitten DG (1976) Z Phys Chem NF 101:151
Nerbonne JM, Weiss RG (1978) J Am Chem Soc 100:2571
Wolff T, Muller N (1983) J Photochem 23:131
Wolff T, Muller N (1983) J Photochem 22:61
Takagi K, Miyake N, Nakamura E, Usami H, Sawaki Y (1988) J Chem Soc Faraday Trans I 84:3475
Ueno A, Moriwaki F, Iwama Y, Suzuki I, Osa T, Ohta T, Nozoe S (1991) J Amer Chem Soc 113:7034
Usami H, Takagi K, Sawaki Y (1992) J Chem Soc Faraday Trans 88:77
Takagi K, Suddaby BR, Vadas SL, Backer CA, Whitten DG (1986) J Amer Chem Soc 108:7865
Takagi K, Fukaya H, Miyake N, Sawaki Y (1988) Chem Lett 1053
Takagi K, Nambara E, Usami H, Itoh M, Sawaki Y (1991) J Chem Soc Perkin Trans I 655.
Takagi K, Itoh M, Usami H, Imae T, Sawaki Y (1994) J Chem Soc Perkin Trans 2 1003
Imae T, Tsubota T, Okamura H, Mori O, Takagi K, Itoh M, Sawaki Y, J Phys Chem, in press
Imae T, Ikeda S (1987) Colloid Polym Sci 265:1090
Imae T (1988) J Phys Chem 92:5721 (1989) J Colloid Interface Sci 127:256
Kratochvil P (1987) Classical Light Scattering from Polymer Solutions; Elsevier: Amsterdam
Burchard W (1983) Adv Polym Sci 48:1
Yamakawa H (1971) Modern Theory of Polymer Solution; Harper and Row: New York
Imae T (1990) J Phys Chem 94:5953
Imae T, Kohsaka T (1992) J Phys Chem 96:10030
Biresaw G, McKengie DC, Bunton CA, Nicoli D F (1985) J Phys Chem 89:5144
Okamura H, Imae T, Furusaka M submitting
Van de Sande W, Persoons A (1985) J Phys Chem 89:404
Van Zanten JH, Monbouguette HG (1991) J Colloid Interface Sci 146:330
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Imae, T., Mori, O., Takagi, K. et al. Self-assembly formation of amphiphilic molecules mixed with photoreactive, aromatic unsaturated-acids: examination by light scattering. Colloid Polym Sci 273, 579–583 (1995). https://doi.org/10.1007/BF00658688
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DOI: https://doi.org/10.1007/BF00658688