Skip to main content
SpringerLink
Log in

Synthesis and characterization of novel bonded phases for reversed-phase liquid chromatography

  • Originals
  • Published:
Chromatographia Aims and scope Submit manuscript

Summary

The results of a chromatographic comparison of newly synthesized reversed-phase bonded stationary phases incorporating various degrees of unsaturation or rigidity are presented. The phases studied included monomeric n-decyl, polymeric n-decyl, adamantyl, norpinyl, decadiynyl, phenylbutyl and β-naphthyl bonded phases. The effect of bonded phase structure on retention is discussed for selected aromatic solutes.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. L. C. Sander, S. A. Wise, “Investigations of Selectivity in RPLC of Polycyclic Aromatic Hydrocarbons” inAdvances in Chromatography, Vol. 25,J. C. Giddings, ed., Marcel Dekker, Inc., N. Y., (1980) 139–217.

    Google Scholar 

  2. N. Tanaka, K. Sakagami, M. Araki, J. Chromatogr.,199, 327 (1980).

    Article  CAS  Google Scholar 

  3. N. Tanaka, K. Sakagami, M. Araki, Chem. Let., 587 (1980).

  4. H. J. Issaq, S. D. Fox, K. Lindsey, J. H. McConnell, D. E. Weiss, J. Liq. Chromatogr.,10 (1), 49 (1987).

    CAS  Google Scholar 

  5. A. Tchapla, H. Colin, G. Guiochon, Anal. Chem.,56, 621 (1984).

    CAS  Google Scholar 

  6. C. H. Lochmüller, D. R. Wilder, J. Chromatogr. Sci.,17, 574 (1979).

    Google Scholar 

  7. K. Jinno, K. Kawasaki, Chromatographia,17, 445 (1983).

    CAS  Google Scholar 

  8. T. Welsch, H. Frank, H. Zwanziger, S. Liebisch, W. Engewald, Chromatographia,19, 457 (1984).

    CAS  Google Scholar 

  9. H. Engelhardt, G. Ahr, Chromatographia,14, 227 (1981).

    CAS  Google Scholar 

  10. L. C. Sander, S. A. Wise, Anal. Chem.,59, 2309 (1987).

    Article  CAS  Google Scholar 

  11. S. S. Yang, R. K. Gilpin, Anal. Chem.,59, 2750 (1987).

    Article  CAS  Google Scholar 

  12. C. H. Lochmüller, H. H. Hangac, D. R. Wilder, J. Chromatogr. Sci.,19, 130 (1981).

    Google Scholar 

  13. N. Tanaka, Y. Tokuda, K. Iwaguchi, M. Araki, J. Chromatogr.,239, 761 (1982).

    CAS  Google Scholar 

  14. C. H. Lochmüller, D. R. Wilder, Anal. Chim. Acta,116, 19 (1980).

    Google Scholar 

  15. C. H. Lochmüller, D. R. Wilder, Anal. Chim. Acta.118, 101 (1980).

    Google Scholar 

  16. M. Verzele, N. Van de Velde, Chromatographia20, 239 (1985).

    Article  CAS  Google Scholar 

  17. T. S. Den, A. A. Kettrup, Chromatographia,19, 231 (1984).

    CAS  Google Scholar 

  18. W. R. Melander, J.-X. Huang, Cs. Horvath, R. W. Stout, J. J. Stefano, Chromatographia,20, 641 (1985).

    Article  CAS  Google Scholar 

  19. T. Hanai, H. Hubert, J. Chromatogr.,291, 81 (1984).

    Article  CAS  Google Scholar 

  20. D. B. Marshall, C. L. Cole, D. E. Connolly, J. Chromatogr.,361, 71 (1986).

    CAS  Google Scholar 

  21. C. H. Lochmüller, A. S. Colburn, M. L. Hunnicutt, J. M. Harris, J. Am. Chem. Soc.,106, 4077 (1984).

    Google Scholar 

  22. C. H. Lochmüller, M. L. Hunnicutt, J. F. Mullaney, J. Phys. Chem.,89, 5770 (1985).

    Google Scholar 

  23. D. E. Martire, R. E. Boehm, J. Phys. Chem.,87, 1045 (1983).

    CAS  Google Scholar 

  24. S. A. Wise, L. C. Sander, J. High Res. Chromatogr. & Chromatogr. Comm.,8, 248 (1985).

    CAS  Google Scholar 

  25. L. C. Sander, S. A. Wise, Anal. Chem.,56, 509 (1984).

    Article  Google Scholar 

  26. L. Brandsma, H. D. Verkruijsse, Synthesis of Acetylenes, “Allenes and Cumulenes: A Laboratory Manual”, Elsevier, Amsterdam, 1981, p. 15, 16, 71–73.

    Google Scholar 

  27. A. M. Stalcup, Ph. D. Thesis, Georgetown University, 1988.

  28. R. M. Roberts, J. C. Gilbert, L. B. Rodewald, A. S. Wingrove, “An Introduction to Modern Experimental Organic Chemistry, 2nd ed., Hoft, Rienhart and Winston, Inc., New York, NY, 1974, p. 236–242.

    Google Scholar 

  29. H. D. Durst, G. W. Gokel “Experimental Organic Chemistry”, McGraw-Hill, Inc., New York, NY, 1980, 268–274.

    Google Scholar 

  30. H. Shih-Hsien, S. D. Fazio, S. A. Tomellini, J. B. Crowther, R. A. Hartwick, Chromatographia20, 161 (1985).

    Article  Google Scholar 

  31. B. I. Diamondstone, S. A. Wise, L. C. Sander, J. Chromatogr.,321, 319 (1985).

    Article  CAS  Google Scholar 

  32. A. M. Stalcup, D. E. Martire, S. A. Wise, J. Chromatogr.,442, 1 (1988).

    Article  CAS  Google Scholar 

  33. E. sz. Kovats, Retention in Liquid/Solid Chromatography, in “The Sciences of Chromatography”, J. Chromatogr. Lib., Vol. 32,F. Brunder (ed.), Elsevier, Amsterdam, 1985; p. 205–217.

    Google Scholar 

  34. L. R. Snyder, J. J. Kirkland, “Introduction to Modern Liquid Chromatography”, 2nd ed., John Wiley & Sons, Inc., New York, N.Y., 1979, p. 24–25.

    Google Scholar 

  35. L. C. Sander, S. A. Wise, J. High Res. Chromatogr. & Chromatogr. Comm.,11, 383 (1988), 22.

    Google Scholar 

Download references

Author information

Author notes

  1. A. M. Stalcup

    Present address: Department of Chemistry, University of Missouri-Rolla, 65401, Rolla, MO, USA

Authors and Affiliations

  1. Organic Analytical Research Division, National Institute of Standards and Technology (formerly National Bureau of Standards), 20899, Gaithersburg, MD, USA

    A. M. Stalcup, L. C. Sander & S. A. Wise

  2. Department of Chemistry, Georgetown University, 20057, Washington DC, USA

    D. E. Martire

Authors
  1. A. M. Stalcup
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. D. E. Martire
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. L. C. Sander
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. S. A. Wise
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Stalcup, A.M., Martire, D.E., Sander, L.C. et al. Synthesis and characterization of novel bonded phases for reversed-phase liquid chromatography. Chromatographia 27, 405–411 (1989). https://doi.org/10.1007/BF02319555

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02319555

Key Words

Search

Navigation