Summary
Chiral γ-lactones from the raw flavour extract of strawberries and commercially available fruit-containing products are stereoanalyzed directly by on-line coupling of liquid chromatography (LC) to gas chromatography (GC) and enantiomer separation with 2,6-di-O-pentyl-3-O-acetyl-α-cyclodextrin as the chiral stationary phase.
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References
G. Ohloff Experientia,42, 271 (1986).
A. Mosandl, G. Heusinger, Liebig's Ann. Chem., 1185 (1985).
C. Günther, A. Mosandl, Liebig's Ann. Chem., 2112 (1986).
A. Mosandl, M. Gessner, Z. Lebensm. Unters. Forsch.187, 40 (1988).
A. Mosandl, C. Günther, J. Agric. Food Chem.,37, 413 (1989).
A. Mosandl, A. Kustermann, Z. Lebensm. Unters. Forsch.,189, 212 (1989).
Aromenverordnung i. d. F. des Art. 22 der VO zur Neurodnung lebensmittelrechtlicher Kennzeichnungsvorschriften v. 22.12.1981 (BGBI I S. 1625, 1676), der 1. Änd. v. 10.5.1983 (BGBI I S. 602) und der ZVerkV v. 10.7.1984 (BGBI I S. 897).
A. Mosandl, M. Gessner, C. Günther, W. Deger, G. Singer, J. High Resolut. Chromatogr./Chromatogr. Commun.,10, 67 (1987).
A. Mosandl, U. Palm, C. Günther, A. Kustermann, Z. Lebensm. Unters. Forsch.,188, 148 (1989).
W. A. König, S. Lutz, C. Colberg, N. Schmidt, G. Wenz, E. von der Bey, A. Mosandl, C. Günther, A. Kustermann, J. High Resolut. Chromatogr./Chromatogr. Commun.,11, 621 (1988).
G. Schomburg, H. Husmann, E. Hübinger, W. A. König, J. High Resolut. Chromatogr./Chromatogr. Commun.,7, 404 (1984).
A. Mosandl, U. Hener, U. Hagenauer-Hener, A. Kustermann, J. High Resolut. Chromatogr.,12, 532 (1989).
S. Nitz, H. Kollmannsberger, F. Drawert, Chem. Mikrobiol. Technol. Lebensm.,12, 75 (1989).
A. Mosandl, A. Kustermann, U. Palm, H.-P. Dorau, W. A. König, Z. Lebensm. Unters. Forsch.,188, 517 (1989).
I. L. Davies, K. E. Markides, M. L. Lee, M. W. Kaynor, K. D. Bartle, J. High Resolut. Chromatogr.12, 193 (1989).
K. Grob, B. Schilling, Ch. Walder, J. High Resolut. Chromatogr./Chromatogr. Commun.,9, 95 (1986).
K. Grob, D. Fröhlich, B. Schilling, H.-P. Neukom, P. Nägeli, J. Chromatogr.,295, 601 (1985).
K. Grob Jr., Chromatographia,17, 357 (1983).
K. Grob, B. Schilling, J. Chromatogr.,391, 3 (1987).
F. Munari, A. Trisciani, G. Mapelli, S. Trestianu, K. Grob, J. M. Colin, J. High Resolut. Chromatogr./Chromatogr. Commun.,8, 197 (1985).
F. A. Maris, E. Noroozian, R. R. Otten, R. C. J. M. van Dijk, G. J. de Jong, U. A. Th. Brinkman, J. High Resolut. Chromatogr./Chromatogr. Commun.,11 197 (1988).
Th. Noy, E. Weiss, T. Herps H. Van Cruchten, J. Rijks, J. High Resolut. Chromatogr./Chromatogr. Commun.,11, 181 (1989).
B. Pacciarelli, E. Müller, R. Schneider, K. Grob, W. Steiner, D. Fröhlich, J. High Resolut. Chromatogr./Chromatogr. Commun.,11, 135 (1988).
K. Grob, H.-G. Schmarr, A. Mosandl, J. High Resolut. Chromatogr.,12, 375 (1989).
W. Vogt, K. Jacob in: Sample Introduction in Capillary Gas Chromatography, Vol. 1, (P. Sandra, editor), p. 99, Huthig-Verlag, Heidelberg, 1985.
M. Biedermann, K. Grob, W. Meier, J. High Resolut. Chromatogr./Chromatogr. Comm.,12, 591 (1989).
H.-G. Schmarr, A. Mosandl, K. Grob, J. High Resolut. Chromatogr.12, 721 (1989).
C. J. Little, A. D. Dale, J. A. Whatley, J. A. Wickings, J. Chromatogr.,169, 381 (1979).
K. Grob, Z. Li, J. Chromatogr.,455, 297 (1988).
F. Munari, K. Grob, J. High Resolut. Chromatogr./Chromatogr. Commun.,11, 172 (1988).
B. Schilling, K. Grob, P. Pichler, R. Dubs, B. Brechbühler, J. Chromatogr.,435, 204 (1988).
K. Grob, M. Biedermann, J. Chromatogr.,448, 387 (1988).
K. Grob Jr., H.-P. Neukom, M.-L. Riekkola J. High Resolut. Chromatogr./Chromatogr. Commun.,7, 319 (1984).
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Schmarr, H.G., Mosandl, A. & Grob, K. Stereoisomeric flavour compounds XXXVIII: Direct chirospecific analysis of γ-lactones using on-line coupled LC-GC with a chiral separation column. Chromatographia 29, 125–130 (1990). https://doi.org/10.1007/BF02268697
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DOI: https://doi.org/10.1007/BF02268697