Summary
The adduction constants for the following eight binary systems were measured by gas liquid chromatography, at different temperatures: tetrachloromethane/p-xylene, tetrachloromethane/pseudocumene, chloroform/p-xylene, chloroform/pseudocumene, chloroform/aniline, m-methylphenol/aniline, o-methylphenol/aniline, and o-chlorophenol/aniline. The relationships between the adduction constant and temperature were used to fit the enthalpies and entropies of adduct formation.
Similar content being viewed by others
References
J. R. Conder, C. L. Young, “Physicochemical Measurements by Gas Chromatography”, Chapter 6. John Wiley & Sons, Chichester, 1979.
D. E. Martire, P. Riedel, J. Phys. Chem.72, 3478 (1968).
E. Gil-Av., J. Herling, J. Phys. Chem.66, 1208 (1962).
M. A. Muhs, F. T. Weiss, J. Am. Chem. Soc.84, 4697 (1962).
J.-M. Li, S.-K. Wang, J. Shi, J. Chromatogr. Sci.27, 596 (1989).
G.-K. Zheng, K.-Y. Wang, P. Liu, X.-X. Zhou, Proceedings of the 4th Symposium on Solution Chemistry, Shenyang, 1988, p. 66.
M. L. McGlashan, D. Stubley, H. Watts, J. Chem. Soc.A, 673 (1969).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Feng, X., Wang, S.K. & Shi, J. Measurement of the adduction constant by gas-liquid chromatography. Chromatographia 30, 211–214 (1990). https://doi.org/10.1007/BF02274549
Received:
Revised:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF02274549