Summary
Sensitivities of a solid surface to dispersive and nondispersive (polar) interactions can be readily estimated by a multiple regression analysis of inverse gas chromatographic retention data of a set of probe solutes. This analysis is based on linear free energy relationships (LFERs). The sensitivity to the latter type of interactions can be used as a measure of the surface polarity of the solid. This has been shown in the case of a graphitized carbon fiber and the method is also applicable to other solids.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
S. Dong, M. Brendle, J. B. Donnet, Chromatographia,28, 469 (1989).
J. B. Donnet, S. J. Park, H. Balard, Chromatographia,31, 434 (1991).
R. W. Taft, J.-L. M. Abboud, M. J. Kamlet, M. H. Abraham, J. Solution Chem.,14, 153 (1985).
M. J. Kamlet, R. W. Taft, Acta Chem. Scand.B39, 611 (1985).
M. J. Kamlet, R. M. Doherty, M. H. Abraham, Y. Marcus, R. W. Taft, J. Phys. Chem.,92, 5244 (1988).
M. J. Kamlet, J.-L. M. Abboud, M. H. Abraham, R. W. Taft, J. Org. Chem.,48, 2877 (1983).
M. J. Kamlet, R. W. Taft, P. W. Carr, M. H. Abraham, J. Chem. Soc. Faraday Trans. I,78, 1689 (1982).
J. E. Brady, D. Bjorkman, C. D. Herter, P. W. Carr, Anal. Chem.,56, 278 (1984).
P. C. Sadek, P. W. Carr, R. M. Doherty, M. J. Kamlet, R. W. Taft, M. H. Abraham, Anal. Chem.,57, 2971 (1985).
P. W. Carr, R. M. Doherty, M. J. Kamlet, R. W. Taft, W. Malendar, Cs. Horvath, Anal. Chem.,58, 2674 (1986).
J. H. Park, P. W. Carr, M. H. Abraham, R. W. Taft, R. M. Doherty, M. J. Kamlet, Chromatographia,25, 373 (1988).
J. H. Park, M. D. Jang, S. T. Kim, Bull. Korean Chem. Soc.,11, 297 (1990).
J. H. Park, Bull. Korean Chem. Soc.,11, 568 (1990).
M. H. Abraham, G. J. Buist, P. L. Grellier, R. A. McGill, R. M. Doherty, M. J. Kamlet, R. W. Taft, S. G. Maroldo, J. Chromatogr.,409, 15 (1987).
J. H. Park, P. W. Carr, J. Chromatogr.,465, 123 (1989).
S. Dong, Dissertation, University of Haute Alsace, Mulhouse, France (1989).
S. Dong, M. Brendle, J. B. Donnet, J. Chim. Phys., in press (1991).
S. Ehrenson, J. Org. Chem.,44, 1793 (1979).
M. H. Abraham, P. L. Grellier, D. V. Piior, P. P. Duce, J. J. Morris, P. J. Taylor, J. Chem. Soc. Perkin Trans.II, 699 (1989).
S. Weisberg, Applied Linear Regression, Wiley, New York (1980).
M. H. Abraham, P. L. Grellier, R. A. McGill, J. Chem. Soc. Perkin Trans.II, 797 (1987).
M. H. Abraham, G. S. Whitting, R. M. Doherty, W. J. Shuely, J. Chromatogr.,518, 329 (1990).
J. Li, A. J. Dallas, P. W. Carr, J. Chromatogr.,517, 103 (1990).
P. R. Bevington, Data Reduction and Error Analysis for the Physical Sciences, McGraw-Hill, New York, 1969.
E. F. Meyer, T. A. Renner, K. S. Stec, J. Phys. Chem.,75, 642 (1971).
E. F. Meyer, R. E. Wagner, J. Phys. Chem.,70, 3162 (1966).
E. F. Meyer, C. A. Holtz, J. Chem. Eng. Data,21, 274 (1976).
E. F. Meyer, M. J. Awe, R. E. Wagner, J. Chem. Eng. Data,25, 371 (1980).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Park, J.H., Lee, Y.K. & Donnet, J.B. A study of solid surface polarity using inverse gas chromatographic retention data. Chromatographia 33, 154–158 (1992). https://doi.org/10.1007/BF02275897
Received:
Revised:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF02275897