Skip to main content

Thank you for visiting nature.com. You are using a browser version with limited support for CSS. To obtain the best experience, we recommend you use a more up to date browser (or turn off compatibility mode in Internet Explorer). In the meantime, to ensure continued support, we are displaying the site without styles and JavaScript.

  • Letter
  • Published:

Structure of lithium–sodium β-alumina by powder neutron diffraction

Abstract

THE first structural determination of a β-alumina compound containing two different alkali ions, lithium and sodium, in crystallographically distinct sites in the conducting plane is reported here. The lithium ions are displaced by about 1 Å from the mirror planes. Although such a displacement has been suspected it has not hitherto been confirmed.

This is a preview of subscription content, access via your institution

Access options

Buy this article

Prices may be subject to local taxes which are calculated during checkout

Similar content being viewed by others

References

  1. Roth, W. L. & Farrington, G. C. Science 196, 1332–1334 (1976).

    Article  ADS  Google Scholar 

  2. Chandrashekhar, G. V. & Foster, L. M. Solid St. Commun. 27, 269–273 (1978).

    Article  ADS  CAS  Google Scholar 

  3. Peters, C. R., Bettman, M., Moore, J. W. & Glick, M. D. Acta Crystallogr. B 27, 1826–1834 (1971).

    Article  CAS  Google Scholar 

  4. Radzilowski, R. H. & Kummer, J. T. J. electrochem. Soc. 118, 714–716 (1971).

    Article  CAS  Google Scholar 

  5. Shannon, R. D. Acta Crystallogr. A 32, 751–767 (1976).

    Article  Google Scholar 

  6. Kummer, J. T. Prog. Solid. St. Chem. 7, 141–175 (1972).

    Article  CAS  Google Scholar 

  7. Rietfeld, H. M. J. appl. Crystallogr. 2, 65–71 (1969).

    Article  Google Scholar 

  8. Roth, W. L., Reidinger, F. & LaPlaca, S. in Superionic Conductors (eds Mahan, G. D. & Roth, W. L.) 223–241 (Plenum, New York, 1976).

    Book  Google Scholar 

  9. Collin, G., Boilot, J. P., Kalan, A., Thery, J. & Comes, R. J. Solid St. Chem. 21, 283–292 (1977).

    Article  ADS  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

TOFIELD, B., FARRINGTON, G. Structure of lithium–sodium β-alumina by powder neutron diffraction. Nature 278, 438–439 (1979). https://doi.org/10.1038/278438a0

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1038/278438a0

This article is cited by

Comments

By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.

Search

Quick links

Nature Briefing

Sign up for the Nature Briefing newsletter — what matters in science, free to your inbox daily.

Get the most important science stories of the day, free in your inbox. Sign up for Nature Briefing