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Nonrigid intramolecular rearrangements in AXk compounds with high coordination numbers (k=5, 6, and 7)

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Literature cited

  1. H. S. Gutowsky and A. D. Lier, J. Chem. Phys.,20, 1652 (1952).

    Google Scholar 

  2. H. S. Gutowsky, D. W. McCall, and C. P. Slichter, J. Chem. Phys.,21, 279 (1953).

    Google Scholar 

  3. R. R. Holmes, Pentacoordinated Phosphorus, Vol. 1, Structure and Spectroscopy, American Chemical Society, Washington (1980).

    Google Scholar 

  4. R. R. Holmes, Pentacoordinated Phosphorus, Vol. 2, Reaction Mechanism, American Chemical Society, Washington (1980).

    Google Scholar 

  5. J. P. Jesson and E. L. Muetterties, in: Dynamic Nuclear Magnetic Resonance Spectroscopy, L. M. Jackman and F. A. Cotton, eds., Academic Press, New York (1975).

    Google Scholar 

  6. E. L. Muetterties, Acc. Chem. Res.,3, 266 (1970).

    Google Scholar 

  7. K. W. Hansen and L. S. Bartell, Inorg. Chem.,4, 1775 (1965).

    Google Scholar 

  8. H. Selig, J. H. Holloway, J. Tyson, and H. H. Claassen, J. Chem. Phys.,53, 2559 (1970).

    Google Scholar 

  9. F. A. Miller and R. J. Capwell, Spectrochim. Acta,27A, 125 (1970).

    Google Scholar 

  10. J. P. Lesson and P. Meakon, J. Am. Chem. Soc.,96, 5760 (1974).

    Google Scholar 

  11. E. L. Muetterties, J. Am. Chem. Soc.,91, 1636 (1969).

    Google Scholar 

  12. R. S. Berry, J. Chem. Phys.,32, 933 (1960).

    Google Scholar 

  13. I. Ugi, D. Marguading, H. Klusacek, et al., Acc. Chem. Res.,4, 288 (1971).

    Google Scholar 

  14. R. Gillespie, Molecular Geometry, Van Nostrand Reinhold (1972).

  15. A. Rauk, L. C. Allen, and K. Mislow, J. Am. Chem. Soc.,94, 3035 (1972).

    Google Scholar 

  16. S. K. Shih, S. D. Peyerimhoff, and R. J. Buenker, J. Chem. Soc. Faraday Trans. II,75, 379 (1979).

    Google Scholar 

  17. W. Kutzelnigg, H. Wallmeier, and J. Wasilewski, Theor. Chim. Acta,51, 261 (1979).

    Google Scholar 

  18. W. Kutzelnigg and J. Wasilewski, J. Am. Chem. Soc.,104, 953 (1982).

    Google Scholar 

  19. P. Meakin, E. L. Muetterties, F. N. Tebbe, and J. P. Jesson, J. Am. Chem. Soc.,93, 4701 (1971).

    Google Scholar 

  20. P. Russegger and J. Brickmann, Chem. Phys. Lett.,30, 276 (1975).

    Google Scholar 

  21. A. Strich and A. Veillard, J. Am. Chem. Soc.,95, 5574 (1973).

    Google Scholar 

  22. L. S. Bernstein, S. Abramowitz, and I. W. Levin, J. Chem. Phys.,64, 3228 (1976).

    Google Scholar 

  23. V. P. Spiridonov, A. A. Ischenko, and L. S. Ivashevich, J. Mol. Struct.,72, 153 (1981).

    Google Scholar 

  24. R. Hoffmann, J. M. Howell, and E. L. Muetterties, J. Am. Chem. Soc.,99, 3047 (1972).

    Google Scholar 

  25. E. L. Muetterties and R. A. Schunn, Q. Rev. Chem. Soc.,20, 245 (1966).

    Google Scholar 

  26. D. L. Wilhite and L. Spialter, J. Am. Chem. Soc.,95, 2100 (1973).

    Google Scholar 

  27. A. Keil and W. Kutzelnigg, J. Am. Chem. Soc.,97, 3623 (1975).

    Google Scholar 

  28. A. Strich, Inorg. Chem.,17, 942 (1972).

    Google Scholar 

  29. J. W. Gilije, R. W. Broun, and A. H. Cowley, J. Chem. Soc. Chem. Commun., 15 (1974).

  30. s. B. Pierce and C. D. Cornwell, J. Chem. Phys.,48, 2118 (1968).

    Google Scholar 

  31. A. H. Cowley and R. M. Braun, Inorg. Chem.,12, 491 (1973).

    Google Scholar 

  32. J. Demuynck, A. Strich, and A. Veillard, Nouv. J. Chim.,1, 217 (1977).

    Google Scholar 

  33. J. S. Wood, in: Progress in Inorg. Chem., S. J. Lippard, ed., Interscience, New York, Vol. 16 (1972), p. 227.

    Google Scholar 

  34. G. M. Whitesides and H. L. Mitchell, J. Am. Chem. Soc.,91, 5384 (1969).

    Google Scholar 

  35. T. R. Dyke, A. A. Muenter, W. Klemperer, and M. E. Falconer, J. Chem. Phys.,53, 3382 (1971).

    Google Scholar 

  36. N. Bernal, N. Elliott, and R. Kalanatte, J. Chem. Soc. Chem. Commun., 803 (1971).

  37. S. A. Goldfield and K. N. Raymond, Inorg. Chem.10, 2604 (1971).

    Google Scholar 

  38. H. W. Spiess, R. Grosescu, and V. Haeberler, Chem. Phys.,6, 226 (1974).

    Google Scholar 

  39. M. I. Davis and C. S. Speed, J. Organomet. Chem.,21, 401 (1970).

    Google Scholar 

  40. W. R. Wadt and P. J. Hay, J. Am. Chem. Soc.,101, 5198 (1979).

    Google Scholar 

  41. I. W. Levin, J. Chem. Phys.50, 1031 (1969).

    Google Scholar 

  42. R. R. Holmes, R. M. Dieters, and J. A. Golin, Inorg. Chem.,8, 2612 (1969).

    Google Scholar 

  43. R. R. Holmes and R. M. Dieters, J. Am. Chem. Soc.,90, 5021 (1968).

    Google Scholar 

  44. R. R. Holmes and R. M. Dieters, Inorg. Chem.,7, 2229 (1968).

    Google Scholar 

  45. B. J. Dalton, J. Chem. Phys.,54, 4745 (1971).

    Google Scholar 

  46. N. M. Sergeev, Usp. Khim.,42, 669 (1973).

    Google Scholar 

  47. J. Emsley, J. Feeney, and L. Sutcliffe, High-Resolution NMR Spectroscopy, Pergamon Press (1965).

  48. E. L. Muetterties, W. Mahler, and R. Schmutzler, Inorg. Chem.,2, 613 (1963).

    Google Scholar 

  49. P. C. Lauterbut and F. Ramires, J. Am. Chem. Soc.,90, 6722 (1968).

    Google Scholar 

  50. V. I. Sokolov, Introduction to Theoretical Stereochemistry [in Russian], Nauka, Moscow (1979).

    Google Scholar 

  51. V. I. Minkin, B. Ya. Simkin, and R. M. Minyaev, The Theory of Molecular Structure [in Russian], Vysshaya Shkola, Moscow (1979).

    Google Scholar 

  52. F. Keil and R. Ahlrichs, J. Am. Chem. Soc.,98, 4787 (1976).

    Google Scholar 

  53. E. D. Jemmis, J. Chandrasekhar, and P. V. R. Schleyer, J. Am. Chem. Soc.,101, 527 (1979).

    Google Scholar 

  54. W. H. Tolles and W. D. Cowin, J. Chem. Phys.,36, 1119 (1962).

    Google Scholar 

  55. K. Kimura and S. H. Bauer, J. Chem. Phys.,39, 3172 (1963).

    Google Scholar 

  56. D. F. Smith, J. Chem. Phys.,21, 609 (1953).

    Google Scholar 

  57. N. C. Baird and K. F. Taylor, Can. J. Chem.59, 814 (1981).

    Google Scholar 

  58. L. Radom and H. F. Schaefer, Aust. J. Chem.,28, 2069 (1975).

    Google Scholar 

  59. S. R. Ungemach and H. F. Schaefer, J. Am. Chem. Soc.,97, 1393 (1975).

    Google Scholar 

  60. Y. Yochioka, J. D. Goddard, and H. F. Schaefer, J. Chem. Phys.,74, 1855 (1981).

    Google Scholar 

  61. I. W. Levin and W. C. Harris, J. Chem. Phys.,55, 3048 (1971).

    Google Scholar 

  62. V. L. Pershin, A. I. Boldyrev, and V. I. Kostin, Zh. Neorg. Khim.,29 (1984).

  63. M. B. Zuev, A. E. Smolyar, N. M. Klimenko, and O. P. Charkin, Zh. Strukt. Khin.,20, 379 (1979).

    Google Scholar 

  64. G. Gundersen and K. Hedberg, J. Chem. Phys.51, 2500 (1969).

    Google Scholar 

  65. S. R. Murty and A. K. Mohanty, Indian. J. Phys.,45, 535 (1972).

    Google Scholar 

  66. K. O. Christe and E. C. Curtiss, Inorg. Chem.,12, 2245 (1973).

    Google Scholar 

  67. R. Hoffmann, J. M. Howell, and A. R. Rossi, J. Am. Chem. Soc.,98, 2484 (1976).

    Google Scholar 

  68. W. G. Klemperer, J. Am. Chem. Soc.,95, 380, 2015 (1973).

    Google Scholar 

  69. A. I. Boldyrev, V. G. Zakzhevskii, and O. P. Charkin, Zh. Strukt. Khim.,23, 6, 30 (1982).

    Google Scholar 

  70. N. Serpone and D. G. Bickley, Progr. Inorg. Chem.,17 391 (1972).

    Google Scholar 

  71. D. Britton and J. D. Dunitz, Acta Crystallogr.,29A 362 (1973).

    Google Scholar 

  72. R. Hoffmann, B. F. Beier, E. L. Muetterties, and A. R. Rossi, Inorg. Chem.,16, 511 (1977).

    Google Scholar 

  73. H. B. Thompson and L. S. Bartell, Inorg. Chem.,7, 488 (1968).

    Google Scholar 

  74. W. J. Adams, H. B., Thompson, and L. S. Bartell, J. Chem. Phys.,53, 4040 (1970).

    Google Scholar 

  75. H. H. Claassen, E. L. Gasner, and H. Selig, J. Chem. Phys.,48, 1803 (1968).

    Google Scholar 

  76. N. Bartlett, S. Beaton, L. W. Reeves, and E. J. Wells, Can. J. Chem.,42, 2531 (1964).

    Google Scholar 

  77. E. W. Kaiser, J.S. Muenter, W. Klemperer, and W. E. Falconer, J. Chem. Phys.,53, 53 (1970).

    Google Scholar 

  78. M. J. Rothman, L. S. Bartell, C. S. Ewig and J. R. Van Wazer, J. Chem. Phys.,73, 375 (1980).

    Google Scholar 

  79. K. Leary, D. H. Templeton, A. Zalkin and N. Bartlett, Inorg. Chem.,12, 1717 (1973).

    Google Scholar 

  80. L. S. Bartell, J. Chem. Phys.,46, 4530 (1967).

    Google Scholar 

  81. R. M. Gavin and L. S. Bartell, J. Chem. Phys.,48, 2460 (1968).

    Google Scholar 

  82. T. H. Brown, P. H. Kasai, and P. H. Verner, J. Chem. Phys.,40, 3448 (1964).

    Google Scholar 

  83. R. F. Code, W. E. Falconer, W. Klemperer, and I. Ozier, J. Chem. Phys.,45, 4955 (1966).

    Google Scholar 

  84. W. E. Falconer, A. Buchler, J. L. Stauffer, and W. Klemperer, J. Chem. Phys.,48, 312 (1968).

    Google Scholar 

  85. G. L. Goodman, J. Chem. Phys.,56, 5038 (1972).

    Google Scholar 

  86. H. H. Claassen, G. L. Goodman, and H. Kim, J. Chem. Phys.,56, 5042 (1972).

    Google Scholar 

  87. E. W. Phillips, J. W. D. Connolly, and S. B. Trickey, Chem. Phys. Lett.,17, 203 (1972).

    Google Scholar 

  88. C. Trindle, S. N. Datta, and T. H. Bouman, Int. J. Quant. Chem.,11, 627 (1977).

    Google Scholar 

  89. A. I. Boldyrev and V. G. Zakzhevskii, in: The Current State of the Theory of Atoms and Molecules, Part 2 [in Russian], Vilnius (1977), p. 77.

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Translated from Zhurnal Strukturnoi Khimii, Vol. 25, No. 4, pp. 102–124, July–August, 1984.

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Boldyrev, A.I., Charkin, O.P. Nonrigid intramolecular rearrangements in AXk compounds with high coordination numbers (k=5, 6, and 7). J Struct Chem 25, 599–622 (1985). https://doi.org/10.1007/BF00747249

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  • DOI: https://doi.org/10.1007/BF00747249

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