Skip to main content
Log in

Reaction rate of 1,4-naphthoquinone radical-anion with Wurster's blue radical-cation

  • Brief Communications
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A value was obtained for the rate constant of the reaction of the 1,4-naphthoquinone radical-anion with the Wurster's blue radical-cation in water, which is twice smaller than the theoretical value.

  2. 2.

    The products of the studied reaction are formed in the ground singlet state.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Literature cited

  1. I. V. Khudyakov and V. A. Kuz'min, Usp. Khim.,44, 1748 (1975).

    Google Scholar 

  2. H. Schomburg, H. Staerk, and A. Weller, Chem. Phys. Lett.,22, 1 (1973).

    Google Scholar 

  3. A. Weller and K. Zachariasse, Chem. Phys. Lett.,10, 197 (1971).

    Google Scholar 

  4. I. V. Khudyakov, C. R. H. I. de Jonge, P. P. Levin, and V. A. Kuzmin, Proceedings of the Third Conference on Degradation and Stabilization of Polymers, Moscow (1977), p. 161.

  5. L. Michaelis and I. Granick, J. Am. Chem. Soc.,65., 1747 (1943).

    Google Scholar 

  6. K. B. Patel and P. L. Willson, J. Chem. Soc. Faraday Trans., 1,1973, 814.

    Google Scholar 

  7. V. A. Kuzmin, I. V. Khudyakov, and A. S. Tatikolov, Chem. Phys. Lett.,49, 495 (1977).

    Google Scholar 

  8. P. C. Dwivedi and C. N. R. Rao, J. Chem. Soc. Perkin Trans., 2,1972, 238.

    Google Scholar 

  9. J. Fritisch, S. Tatwawadi, and R. Adams, J. Phys. Chem.,71, 388 (1967).

    Google Scholar 

  10. N. A. Shcheglova and D. N. Shigorin, Zh. Fiz. Khim.,38, 1261 (1964).

    Google Scholar 

  11. R. Z. Sagdeev, K. M. Salikhov, and Yu. N. Molin, Usp. Khim.,46, 569 (1977).

    Google Scholar 

  12. P. Debye, Trans. Electrochem. Soc.,82, 265 (1942).

    Google Scholar 

  13. I. V. Khudyakov and V. A. Kuz'min, Usp. Khim.,47, 39 (1978).

    Google Scholar 

  14. E. F. Caldin, Fast Reactions in Solution, Wiley (1964).

  15. K. I. Zamaraev, Yu. N. Molin, and K. M. Salikhov, Spin Exchange [in Russian], Nauka, Novosibirsk (1977), Section 13.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1384–1387, June, 1979.

The authors are indebted to I. P. Basmanov for assistance in the work.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Khudyakov, I.V., Koroli, L.L. & Kuz'min, V.A. Reaction rate of 1,4-naphthoquinone radical-anion with Wurster's blue radical-cation. Russ Chem Bull 28, 1297–1299 (1979). https://doi.org/10.1007/BF00947408

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00947408

Keywords

Navigation