Conclusions
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1.
The reaction of oxygen with surface-propylene complexes at room temperature on a 0.1% CoO-MgO sample leads to the formation of mild oxidation products with their escape into space.
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2.
The effect of a discrete, “jumplike” liberation of the reaction product was detected in the case of the 0.1% CoO-MgO sample, with a simultaneous sharp increase in the oxygen absorption. This effect is practically absent for the 12% CoO-MgO.
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3.
A possible mechanism was proposed for the reaction of oxygen with surface-propylene complexes.
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Literature cited
T. Z. Tabasaranskaya, A. A. Kadushin, K. N. Spiridonov, and O. V. Krylov, Kinetika i Kataliz,13, 1540 (1972).
D. Shopov and N. Kotsev, Izv. Otd. Khim. Nauki Bulgar. Akad. Nauk,6, 483 (1973).
L. J. Bellamy, Infrared Spectra of Complex Molecules [Russian translation], IL (1963).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1651–1654, July, 1975.
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Kadushin, A.A., Kotsev, N.K., Krylov, O.V. et al. Reaction of oxygen with surface propylene complexes on CoO-MgO solid solutions. Russ Chem Bull 24, 1542–1544 (1975). https://doi.org/10.1007/BF00946440
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DOI: https://doi.org/10.1007/BF00946440