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Effect of solvent composition on dimerization rate of 2,6-diphenyl-4-methoxyphenoxyl radicals

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The rate constants were obtained for the recombination reactions of 2,6-diphenyl-4-methoxyphenoxyl radicals in binary mixtures.

  2. 2.

    The viscosity of the solvent exerts the determining effect on the values of the rate constants in a methanol-cyclohexanol mixture.

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Literature cited

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow

    I. V. Khudyakov, T. A. Kokrashvili, P. P. Levin & V. A. Kuz'min

Authors
  1. I. V. Khudyakov
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  2. T. A. Kokrashvili
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  3. P. P. Levin
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  4. V. A. Kuz'min
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2364–2368, October, 1977.

The authors wish to thank A. I. Burshtein and V. V. Levin for valuable discussion, and also K. de Jonge (AKZO, Research Laboratories, Arnhem) for graciously supplying the reagent.

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Khudyakov, I.V., Kokrashvili, T.A., Levin, P.P. et al. Effect of solvent composition on dimerization rate of 2,6-diphenyl-4-methoxyphenoxyl radicals. Russ Chem Bull 26, 2198–2201 (1977). https://doi.org/10.1007/BF00923658

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  • DOI: https://doi.org/10.1007/BF00923658

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