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Replacement of mercury by gold in organomercury compounds

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A method has been developed for the synthesis of organogold compounds of the aryl, alkenyl, cymantrenyl, and heterocyclic series from organomercury compounds.

  2. 2.

    Either binuclear cationic complexes of gold with the general formula [R(AuPPh3)2]BF4 or monogold organic compounds with the general formula RAuPPh3 form, depending on the nature of the radial in the organomercury compound.

  3. 3.

    Previously unknown organogold compounds with the general formula RAuPPh3 have been obtained from the binuclear cationic complexes of gold under the action of triphenylphosphine.

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Literature cited

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Authors and Affiliations

  1. M. V. Lomonosov Moscow State University, USSR

    A. N. Nesmeyanov, É. G. Perevalova, O. B. Afanasova, M. V. Tolstaya & K. I. Grandberg

Authors
  1. A. N. Nesmeyanov
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  2. É. G. Perevalova
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  3. O. B. Afanasova
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  4. M. V. Tolstaya
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  5. K. I. Grandberg
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1118–1122, May, 1978.

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Nesmeyanov, A.N., Perevalova, É.G., Afanasova, O.B. et al. Replacement of mercury by gold in organomercury compounds. Russ Chem Bull 27, 969–973 (1978). https://doi.org/10.1007/BF00929002

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  • DOI: https://doi.org/10.1007/BF00929002

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