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Reaction chromato-mass spectrometry Communication 7. Deuterium exchange in a chromato-mass spectrometer column in the study of aliphatic alcohols and carbonyl compounds

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A column has been proposed (KOD dispersed in SE-30 on Chromatone W) that insures deuterium exchange of enolizable H atoms in carbonyl compounds directly in the inlet system of a chromato-mass spectrometer, in order to study the structures of aliphatic alcohols and carbonyl compounds and the mechanisms of their fragmentation under electron impact.

  2. 2.

    Application of this method to ethyl 3-ethylpentyl ketone and ethyl 3-ethylheptyl ketone disclosed two new fragmentation paths under electron impact.

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Literature cited

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Authors and Affiliations

  1. A. V. Topchiev Institute of Petrochemical Synthesis, Academy of Sciences of the USSR, Moscow

    A. I. Mikaya, A. V. Antonova, V. G. Zaikin & N. S. Prostakov

  2. P. Lumumba Peoples' Freedom University, Moscow

    A. I. Mikaya, A. V. Antonova, V. G. Zaikin & N. S. Prostakov

Authors
  1. A. I. Mikaya
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  2. A. V. Antonova
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  3. V. G. Zaikin
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  4. N. S. Prostakov
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Additional information

For Communication 6, see [1].

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 827–830, April, 1985.

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Mikaya, A.I., Antonova, A.V., Zaikin, V.G. et al. Reaction chromato-mass spectrometry Communication 7. Deuterium exchange in a chromato-mass spectrometer column in the study of aliphatic alcohols and carbonyl compounds. Russ Chem Bull 34, 748–751 (1985). https://doi.org/10.1007/BF00948051

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  • DOI: https://doi.org/10.1007/BF00948051

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