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Electronegativity scheme for reactions involving radical addition to vinyl monomers

  • Physical Chemistry
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Bulletin of the Russian Academy of Sciences, Division of chemical science Aims and scope

Abstract

The concept of the apparent electronegativity of a reaction site has been introduced. This has been used to develop a new scheme for calculating the relative rate constants of addition of radicals with different structures to vinyl monomers. The parameters of the scheme are given for 40 reagents. The results of a comparison of calculated and literature rate constants of addition are presented.

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Authors
  1. A. V. Sokolov
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Additional information

Institute of Nonaqueous Solution Chemistry, Russian Academy of Sciences, 150003 Ivanovo. Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 10, pp. 2238–2245, October, 1992.

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Sokolov, A.V. Electronegativity scheme for reactions involving radical addition to vinyl monomers. Russ Chem Bull 41, 1750–1755 (1992). https://doi.org/10.1007/BF00863803

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  • DOI: https://doi.org/10.1007/BF00863803

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