Abstract
The reaction of [2-(dimethylaminomethyl)]cymantrenyl]lithium with ytterbium diiodide affords [2-(dimethylaminomethyl)cymantrenyl]ytterbium iodide or bis[2-(dimethylaminomethyl)cymantrenyl]ytterbium depending on the ratio of the starting reactants. Reactions of these complexes with a series of electrophiles (H2O, Me3SiCl, MeCOCl, HgCl2, PhCOCl) were studied and the corresponding derivatives of cymantrene were prepared in high yields.
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No.3, pp. 531–533, March, 1994.
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Suleimanov, G.Z., Zulfugarly, E.A., Kazimirchuk, E.I. et al. Synthesis and properties of mono- and bis[2-(dimethylaminomethyl)]cymantrenyl derivatives of ytterbium. Russ Chem Bull 43, 491–493 (1994). https://doi.org/10.1007/BF01169733
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DOI: https://doi.org/10.1007/BF01169733