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Electrochemical polymerization of N-methyl-10,10-dimethylphenazasiline

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Abstract

N-methyl-10,10-dimethylphenazasiline (SIN) was polymerized by electrochemical oxidation at +1.3 V in methylene chloride. Acid-base equilibria in solution between the heterocyclic nitrogen and the protons produced by the coupling reaction were detected. The oxidized polymer deposits on platinum or ITO electrodes to give strongly adherent and electrochromic coatings.

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Authors and Affiliations

  1. Istituto di Fotochimica e Radiazioni d'Alta Energia del Consiglio Nazionale delle Ricerche, via De' Castagnoli, 1-40126, Bologna, Italy

    G. Casalbore Miceli, G. Beggiato, S. S. Emmi & A. Geri

  2. Istituto di Polarografia ed Elettrochimica Preparativa del Consiglio Nazionale delle Ricerche, Corso Stati Uniti, 4-35100, Padova, Italy

    S. Daolio

  3. Istituto dei Composti del Carbonio Contenenti Eteroatomi e loro Applicazioni, via Tolara di Sotto, Ozzano Emilia, Bologna, Italy

    L. Favaretto & D. Pietropaolo

Authors
  1. G. Casalbore Miceli
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  2. G. Beggiato
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  3. S. S. Emmi
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  4. A. Geri
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  5. S. Daolio
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  6. L. Favaretto
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  7. D. Pietropaolo
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Miceli, G.C., Beggiato, G., Emmi, S.S. et al. Electrochemical polymerization of N-methyl-10,10-dimethylphenazasiline. J Appl Electrochem 20, 989–995 (1990). https://doi.org/10.1007/BF01019577

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  • DOI: https://doi.org/10.1007/BF01019577

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