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PLUSH TACSY: Homonuclear planar TACSY with two-band selective shaped pulses applied to Cα,C′ transfer and Cβ,Caromatic correlations

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Summary

A new homonuclear Hartmann-Hahn-type mixing scheme is introduced that effects coherence transfer between resonances in two separated frequency bands. The mixing scheme relies on the irradiation of two-band selective shaped pulses that are expanded in an MLEV-16 supercycle. Similar to heteronuclear Hartmann-Hahn experiments, a planar effective coupling tensor is created. This novel mixing scheme is applied to Cα,C′ transfer and to the transfer between Cβ and aromatic carbon spins.

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Author notes

  1. T. Carlomagno

    Present address: Department of Chemistry, University of Naples ‘Federico II’, Via Mezzocannone 4, I-80134, Naples, Italy

  2. M. Sattler

    Present address: Department 47G, AP10, Abbott Laboratories, 60064, Abbott Park, IL, USA

  3. M. G. Schwendinger

    Present address: Department of Dermatology, University of Innsbruck, Anichstrasse 35, A-6020, Innsbruck, Austria

Authors and Affiliations

  1. Institute of Organic Chemistry, University of Frankfurt, Marie Curie Strasse 11, D-60439, Frankfurt, Germany

    T. Carlomagno, M. Maurer, M. Sattler, M. G. Schwendinger, S. J. Glaser & C. Griesinger

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  1. T. Carlomagno
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  2. M. Maurer
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  3. M. Sattler
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  4. M. G. Schwendinger
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  5. S. J. Glaser
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  6. C. Griesinger
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Carlomagno, T., Maurer, M., Sattler, M. et al. PLUSH TACSY: Homonuclear planar TACSY with two-band selective shaped pulses applied to Cα,C′ transfer and Cβ,Caromatic correlations. J Biomol NMR 8, 161–170 (1996). https://doi.org/10.1007/BF00211162

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  • DOI: https://doi.org/10.1007/BF00211162

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