Abstract
Nanocrystalline materials, with a grain size of typically <100 nm, are a new class of materials with properties vastly different from and often superior to those of the conventional coarse-grained materials. These materials can be synthesized by a number of different techniques and the grain size, morphology, and composition can be controlled by controlling the process parameters. In comparison to the coarse-grained materials, nanocrystalline materials show higher strength and hardness, enhanced diffusivity, and superior soft and hard magnetic properties. Limited quantities of these materials are presently produced and marketed in the US, Canada, and elsewhere. Applications for these materials are being actively explored. The present article discusses the synthesis, structure, thermal stability, properties, and potential applications of nanocrystalline materials.
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References
C. Suryanarayana, Inter. Mater. Rev. 40 (1995) 41.
J.M. Silcock, T.J. Heal and H.K. Hardy, J. Inst. Metals 82 (1953–54) 239.
J.B. Cohen, Metall. Trans. 23A (1992) 2685.
R.M. Scanlan, W.A. Fietz and E.F. Koch, J. Appl. Phys. 46 (1975) 2244.
A.A. Voevodin, S.V. Prasad and J.S. Zabinski, J. Appl. Phys. 82 (1997) 855.
H. Gleiter, Prog. Mater. Sci. 33 (1989) 223.
R. Uyeda, Prog. Mater. Sci. 35 (1991) 1.
R.W. Siegel, in: Processing of Metals and Alloys, Materials Science and Technology-A Comprehensive Treatment, Vol. 15, ed. R.W. Cahn (VCH, Weinheim, Germany, 1991) p. 583.
R.W. Siegel, NanoStruct. Mater. 4 (1994) 121.
H. Gleiter, NanoStruct. Mater. 6 (1995) 3.
C. Suryanarayana and C.C. Koch, in: Non-Equilibrium Processing of Materials, ed. C. Suryanarayana (Elsevier Science, Oxford, UK, 1999) p. 313.
C.C. Koch and C. Suryanarayana, in: Microstructure and Properties of Materials, Vol. 2, ed. J.C.M. Li (World Scientific Publishing Corp., Singapore, 2000) p. 359.
R.D. Shull and J.M. Sanchez eds., Nanophases and Nanocrystalline Structures (TMS, Warrendale, PA, 1993).
G.C. Hadjipanayis and R.W. Siegel, eds., Nanophase Materials: Synthesis, Properties, Applications (Kluwer Academic Publishers, Dordrecht, The Netherlands, 1994).
C. Suryanarayana, J. Singh and F.H. Froes, eds., Processing and Properties of Nanocrystalline Materials (TMS, Warrendale, PA, 1996).
D.L. Bourell, ed., Synthesis and Processing of Nanocrystalline Powder (TMS, Warrendale, PA, 1996).
A.S. Edelstein and R.C. Cammarata, eds., Nanomaterials: Synthesis, Properties, and Applications (Inst. Physics, Bristol, UK, 1996).
E. Ma, B. Fultz, R.D. Shull, J. Morral and P. Nash, eds., Chemistry and Physics of Nanostructures and Related Non-Equilibrium Materials (TMS, Warrendale, PA, 1997).
C. Suryanarayana and F.H. Froes, Metall. Trans. 23A (1992) 1071.
K. Lu, Mater. Sci. Eng. Reports R 16 (1996) 161.
R.W. Siegel, MRS Bulletin 15(10) (1990) 60.
C.G. Granqvist and R.A. Buhrman, J. Appl. Phys. 47 (1976) 2200.
H. Konrad, T. Haubold, R. Birringer and H. Gleiter, NanoStruct. Mater. 7 (1996) 605.
W. Chang, G. Skandan, S.C. Danforth, B.H. Kear and H. Hahn, NanoStruct. Mater. 4 (1994) 507.
C.C. Koch, NanoStruct. Mater. 2 (1993) 109; and 9 (1997) 13.
C. Suryanarayana, Prog. Mater. Sci. 46 (2001) 1.
R.Z. Valiev, in: Nanophase Materials: Synthesis, Properties, Applications, eds. G.C. Hadjipanayis and R.W. Siegel (Kluwer Academic Publishers, Dordrecht, The Netherlands, 1994) p. 275; NanoStruct. Mater. 6 (1995) 73.
Y. Saito, H. Utsunomiya, N. Tsuji and T. Sakai, Acta Mater. 47 (1999) 579.
B.H. Kear and L.E. McCandlish, NanoStruct. Mater. 3 (1993) 19; B.H. Kear and P.R. Strutt, NanoStruct. Mater. 6 (1995) 227.
U. Erb, NanoStruct. Mater. 6 (1995) 533.
I. Bakonyi, E. Toth-Kadar, J. Toth, T. Tarnoczi and A. Cziraki, in: Processing and Properties of Nanocrystalline Materials, eds. C. Suryanarayana et al. (TMS, Warrendale, PA, 1996) p. 465.
D.S. Lashmore and M.P. Dariel, in: Encyclopedia of Materials Science and Engineering, ed. R.W. Cahn (Pergamon Press, Oxford, UK, 1988) suppl. Vol. 1, p. 136.
C. Cheung, D. Wood and U. Erb, in: Processing and Properties of Nanocrystalline Materials, eds. C. Suryanarayana et al. (TMS, Warrendale, PA, 1996) p. 479.
Y. Yoshizawa, S. Oguma and K.J. Yamauchi, J. Appl. Phys. 64 (1988) 6044.
K. Lu, in: Processing and Properties of Nanocrystalline Materials, eds. C. Suryanarayana et al. (TMS, Warrendale, PA, 1996) p. 23.
U. Köster, Mater. Sci. Forum 235–238 (1997) 377.
M.L. Trudeau, in: Nanophase Materials: Synthesis, Properties, Applications, eds. G.C. Hadjipanayis and R.W. Siegel (Kluwer Academic Publishers, Dordrecht, The Netherlands, 1994) p. l53.
R.L. Bickerdike, D. Clark, J.N. Easterbrook, G. Hughes, W.N. Mair, P.G. Partridge and H.C. Ranson, Internat. J. Rapid Solidification 1 (1984–85) 305.
G. Liu, Adv. Mater. 9 (1997) 437.
M.N. Rittner and T. Abraham, JOM 50(1) (1998) 36.
K. Okazaki, in: Advanced Synthesis of Engineered Structural Materials, eds. J.J. Moore et al. (ASM International, Materials Park, OH, 1993) p. 197.
M.J. Mayo, Internat. Mater. Rev. 41 (1996) 85.
R.J. Dowding, J.J. Stiglich and T.S. Sudarshan, in: Advances in Powder Metallurgy & Particulate Materials-1994, Vol. 5, eds. C. Lall and A.J. Neupaver (Metal Powder Industries Federation, Princeton, NJ, 1994) p. 45.
J.R. Groza, in: Non-Equilibrium Processing of Materials, ed. C. Suryanarayana (Elsevier Science, Oxford, UK, 1999) p. 347.
C. Suryanarayana and G.E. Korth, Met. and Mater. 5 (1999) 121.
G.W. Nieman and J.R. Weertman, in: Proc. M.E. Fine Symposium, eds. P.K. Liaw et al. (TMS, Warrendale, PA, 1991) p. 243.
J. Weismüller, J. Löfler, C. Krill, R. Birringer and H. Gleiter, in preparation; quoted in [54].
X.D. Liu, K. Lu, B.Z. Ding and Z.Q. Hu, NanoStruct. Mater. 2 (1993) 581.
M.L. Sui and K. Lu, Mater. Sci. Eng. A179–180 (1994) 541.
X.D. Liu, H.Y. Zhang, K. Lu and Z.Q. Hu, J. Phys. C 6 (1994) L497.
H.Y. Zhang, K. Lu and Z.Q. Hu, J. Phys. C 7 (1995) 5327.
D. Chen, NanoStruct. Mater. 4 (1994) 753.
K. Kimoto and I. Nishida, J. Phys. Soc. Jap. 22 (1967) 744.
J. Weismüller, in: Synthesis and Processing of Nanocrystalline Powder, ed. D.L. Bourell (TMS, Warrendale, PA, 1996) p. 3.
J. Weismüller, J. Löfler and M. Kebler, NanoStruct. Mater. 6 (1995) 105.
R. Birringer, in: Nanophase Materials: Synthesis, Properties, Applications, eds. G.C. Hadjipanayis and R.W. Siegel (Kluwer Academic Publishers, Dordrecht, The Netherlands, 1994) p. 157.
R.W. Siegel, in: Materials Interfaces: Atomic Level Structure and Properties, eds. D. Wolf and S. Yip (Chapman & Hall, London, UK, 1992) p. 431.
H. Ouyang, B. Fultz and H. Kuwano, in: Nanophases and Nanocrystalline Structures, eds. R.D. Shull and J.M. Sanchez (TMS, Warrendale, PA, 1993) p. 95. C. Suryanarayana, C.C. Koch / Nanocrystalline materials 43
S.R. Phillpot, D. Wolf and H. Gleiter, J. Appl. Phys. 78 (1995) 847.
Z. Horita, D.J. Smith, M. Furukawa, M. Nemoto, R.Z. Valiev and T.G. Langdon, J. Mater. Res. 11 (1996) 1880.
D.H. Ping, D.X. Li and H.Q. Ye, J. Mater. Sci. Lett. 14 (1995) 1536.
T.R. Malow and C.C. Koch, in: Synthesis and Processing of Nanocrystalline Powder, ed. D.L. Bourell (TMS, Warrendale, PA, 1996) p. 33.
B. Günther, A. Kumpmann and H.D. Kunze, Scripta Metall. Mater. 27 (1992) 833.
J. Eckert, J.C. Holzer and W.L. Johnson, J. Appl. Phys. 73 (1993) 131.
T.R. Malow and C.C. Koch, Acta Mater. 45 (1997) 2177.
V.Y. Gertsman and R. Birringer, Scripta Metall. Mater. 30 (1994) 577.
C.E. Krill, R. Klein, S. Janes and R. Birringer, Mater. Sci. Forum 179–181 (1995) 443.
H. Hahn, J. Logas and R.S. Averback, J. Mater. Res. 5 (1990) 609.
J. Horvath, Defect & Diff. Forum 66–69 (1989) 207.
S. Schumacher, R. Birringer, R. Strauss and H. Gleiter, Acta Metall. 37 (1989) 2485.
B.S. Bokstein, H.D. Bröse, L.I. Trusov and T.P. Khvostantseva, NanoStruct. Mater. 6 (1995) 873.
E. Ivanov, Mater. Sci. Forum 88–90 (1992) 475.
R.W. Siegel and H. Hahn, in: Current Trends in the Physics of Materials, ed. M. Youssouff (World Sci. Pub. Co., Singapore, 1987) p. 403.
J. Karch, R. Birringer and H. Gleiter, Nature 330 (1987) 556.
M.S. Choudry, J.A. Eastman, R.J. DiMelfi and M. Dollar, Scripta Mater. 37 (1997) 843.
K. Lu and M.L. Sui, Acta Metall. Mater. 43 (1995) 3325.
T. Turi and U. Erb, Mater. Sci. & Eng. A204 (1995) 34.
E. Hellstern, H.J. Fecht, Z. Fu and W.L. Johnson, J. Appl. Phys. 65 (1989) 305.
H.Y. Bai, L. Luo, D. Jin and J.R. Sun, J. Appl. Phys. 79 (1996) 361.
M.L. Steigerwald and L.E. Brus, Ann. Rev. Mater. Sci. 19 (1989) 471.
G. Skandan, H. Hahn and J.C. Parker, Scripta Metall. Mater. 25 (1991) 2389.
G.D. Stucky and J.E. MacDougall, Science 27 (1990) 669.
D.G. Morris, in: Mechanical Properties of Nanostructured Materials, Materials Science Foundations, Vol. 2 (Trans. Tech. Publ., Zürich, Switzerland, 1998).
L. Wong, D. Ostrander, U. Erb, G. Palumbo and K.T. Aust, in: Nanophases and Nanocrystalline Structures, eds. R.D. Shull and J.M. Sanchez (TMS, Warrendale, PA, 1993) p. 85.
T.D. Shen, C.C. Koch, T.Y. Tsui and G.M. Pharr, J. Mater. Res. 10 (1995) 2892.
A.M. El-Sherik, U. Erb, V. Krstic, B. Szpunar, M.J. Aus, G. Palumbo and K.T. Aust, MRS Symp. Proc. 286 (1993) 173.
C.C. Koch, D.G. Morris, K. Lu and A. Inoue, MRS Bulletin 24(2) (1999) 54.
P.G. Sanders, M. Rittner, E. Kiedaisch, J.R. Weertman, H. Kung and Y.C. Lu, NanoStruct. Mater. 9 (1997) 433.
A. Inoue, N. Nakazato, Y. Kawamura and T. Masumoto, Mater. Sci. & Eng. A179/180 (1994) 654.
S.X. McFadden, R.S. Mishra, R.Z. Valiev, A.P. Zhilyaev and A.K. Mukherjee, Nature 398 (1999) 684.
R.W. Siegel, Mater. Sci. Forum 235–238 (1997) 851.
K. Lu, Y.Z. Wang, W.D. Wei and Y.Y. Li, Adv. Cryog. Mater. 38 (1991) 285.
X.D. Liu, B.Z. Ding, Z.Q. Hu, K. Lu and Y.Z. Wang, Physica B 192 (1993) 345.
X.D. Liu, J.T. Wang and B.Z. Ding, Scripta Metall. Mater. 28 (1993) 59.
J.T. Lee, J.H. Hwang, J.J. Mashek, T.O. Mason, A.E. Miller and R.W. Siegel, J. Mater. Res. 10 (1995) 2295.
R.N. Viswanath, S. Ramasamy, R. Ramamoorthy, P. Jayavel and T. Nagarajan, NanoStruct. Mater. 6 (1995) 993.
R.H. Yu, X.X. Zhang, J. Tejada, M. Knobel, P. Tiberto and P. Allia, J. Phys. D 28 (1995) 1770.
C.E. Krill, F. Merzoug, W. Krauss and R. Birringer, NanoStruct. Mater. 9 (1997) 455.
U. Erb, G. Palumbo, B. Szpunar and K.T. Aust, NanoStruct. Mater. 9 (1997) 261.
G. Herzer, Scripta Metall. Mater. 33 (1995) 1741.
A. Makino, A. Inoue and T. Masumoto, NanoStruct. Mater. 6 (1995) 985.
A. Makino, A. Inoue and T. Masumoto, Mater. Trans. Jpn. Inst. Metals 36 (1995) 924.
L. Schultz, J. Wecker and E. Hellstern, J. Appl. Phys. 61 (1987) 3583.
P.A.I. Smith, J. Ding, R. Street and P.G. McCormick, Scripta Mater. 34 (1996) 61.
R.D. Shull, R.D. McMichael and J.J. Ritter, NanoStruct. Mater. 2 (1993) 205.
R. Rofagha, U. Erb, D. Ostrander, G. Palumbo and K.T. Aust, NanoStruct. Mater. 2 (1993) 1.
D.D. Beck and R.W. Siegel, J. Mater. Res. 7 (1992) 2840.
L. Zaluski, A. Zaluska, P. Tessier, J.O. Ström-Olsen and R. Schulz, Mater. Sci. Forum 225–227 (1996) 853.
K.Z. Chen, Z.K. Zhang, Z.L. Cui, D.H. Zuo and D.Z. Yang, NanoStruct. Mater. 8 (1997) 205.
M.L. Trudeau and J.Y. Ying, NanoStruct. Mater. 7 (1996) 245.
G. Das, Ceram. Eng. & Sci. Proc. 17 (1996) 25.
Adv. Mater. Proc. 146(4) (1994) 25.
L.E. McCandlish, V. Kevorkian, K. Jia and T.E. Fischer, in: Advances in Powder Metallurgy & Particulate Materials-1994, Vol. 5, eds. C. Lall and A.J. Neupaver (Metal Powder Industries Federation, Princeton, NJ, 1994) p. 329.
M. Gell, Mater. Sci. & Eng. A 204 (1995) 246.
F. Davanloo, T.J. Lee, H. Park, J.H. You and C.B. Colins, J. Mater. Res. 8 (1993) 3090.
A. Berkowitz, in: Nanomaterials: Synthesis, Properties, and Applications, eds. A.S. Edelstein and R.C. Cammarata (Institute of Physics, Bristol, 1996) p. 569.
J.H. Judy, MRS Bulletin 15(3) (1990) 63.
M.P. Sharrock, MRS Bulletin 15(3) (1990) 53.
G. Vitulli, E. Pitzalis, A. Verrazzani, P. Pertici, P. Salvadori and G. Martra, Mater. Sci. Forum 235–238 (1997) 929.
J.H. Sinfelt and G.D. Meitzner, Accounts Chem. Res. 26 (1993) 1.
D.R. Rolison, in: Nanomaterials: Synthesis, Properties, and Applications, eds. A.S. Edelstein and R.C. Cammarata (Institute of Physics, Bristol, 1996) p. 305.
P. Tessier, L. Zaluski, A. Zaluska, J.O. Ström-Olsen and R. Schulz, Mater. Sci. Forum 225–227 (1996) 869.
M.L. Wasz, R.B. Schwarz, S. Srinivasan and M.P.S. Kumar, Mater. Res. Soc. Symp. Proc. 393 (1995) 237.
C.H. Smith, in: Rapidly Solidified Alloys: Processes, Structures, Properties, Applications, ed. H.H. Liebermann (Marcel-Dekker, New York, 1993) p. 617.
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Suryanarayana, C., Koch, C. Nanocrystalline materials – Current research and future directions. Hyperfine Interactions 130, 5–44 (2000). https://doi.org/10.1023/A:1011026900989
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DOI: https://doi.org/10.1023/A:1011026900989