Skip to main content
SpringerLink
Log in

Use of in situ Mössbauer spectroscopy for electrochemical reactions involving57Fe

  • Surface Phenomena, Catalysis, Corrosion
  • Published:
Hyperfine Interactions Aims and scope Submit manuscript

Abstract

An electrochemical cell and relevant electrodes have been carried out in order to study in situ various electrochemical reactions involving iron using57Fe Mössbauer resonance. The electrochemical behaviour of iron in strongly alkaline solution (KOH 5N) in the potential range (−1200<E<−200 mV) has been examined. The introduction of sulfide ions in this electrolyte leads to the formation of a new phase, the mackinawite FeS. Optimized electrochemical conditions for growing a FeS deposit on an iron electrode have been specified.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. W.E. O'Grady and O'M. Bockris, Surf. Sci. 38 (1973) 249.

    Article  Google Scholar 

  2. C. Fierro, R.E. Carbonio, D. Scherson and E.B. Yeager, J. Phys. Chem. 91 (1987) 6579.

    Article  Google Scholar 

  3. U. Stumm, W. Meigel and P. Gütlich, Hyp. Int. 28 (1986) 923.

    Article  Google Scholar 

  4. J. Elridge and R.W. Hoffman, J. Electrochem. Soc. 136 (1989) 955.

    Google Scholar 

  5. C. Chanson, L. Fournès an J-C. Grenier, C. R. Acad. Sci. Paris 303 (1986) 1633.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Laboratoire de Chimie du Solide du C.N.R.S., Université de Bordeaux I, 33 405, Talence-Cedex, France

    L. Fournes, J-C. Grenier, A. Wattiaux & M. Pouchard

  2. Département Accumulateurs, SAFT, 111-113 Bd Alfred Daney, 33 074, Bordeaux-Cedex, France

    C. Chanson

  3. Institute of Inorganic Chemistry, Center for Chemical Research Slovak Academy of Sciences, 842 36, Bratislava, Czechoslovakia

    P. Bezdicka

Authors
  1. L. Fournes
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. J-C. Grenier
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. C. Chanson
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. P. Bezdicka
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. Wattiaux
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. M. Pouchard
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Fournes, L., Grenier, JC., Chanson, C. et al. Use of in situ Mössbauer spectroscopy for electrochemical reactions involving57Fe. Hyperfine Interact 57, 1829–1832 (1990). https://doi.org/10.1007/BF02405729

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02405729

Keywords

Search

Navigation