Skip to main content
SpringerLink
Log in

Crystal structure of [Yb (NO3)3 (phen) (H2O)] · (12-crown-4)

  • Published:
Journal of inclusion phenomena and molecular recognition in chemistry Aims and scope Submit manuscript

Abstract

The title complex was prepared by reacting Yb(NO3)3 (12-crown-4) with 1,10-phenanthroline (hereafter phen) in acetone. It crystallized in the triclinic space group\(P\bar 1\) witha=10.095(5),b=17.415(4),c=8.710(2) Å α=92.45(2), β=115.83(3), γ=74.08(3)0 andD c=1.85 g cm−3;Z=2. The metal ion in this complex is nine-coordinated to three bidentate nitrate ions, two nitrogen atoms of a phen and a water molecule. The crown ligand is hydrogen bonded to the coordination water molecule. The symmetry change of the crown ether is also discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. J.C.G. Bunzli:Handbook on the Physics and Chemistry of the Rare Earths, Vol. 9, p. 321 (1987).

    Google Scholar 

  2. R.D. Rogers, E.J. Voss, and R.D. Etzenhouser:Inorg. Chem. 27, 533 (1988).

    Google Scholar 

  3. Zhu WenXiang, Yang RuiNa, Zhao JiZhou, Luo BaoSheng, and Chen LiaoRong:Chinese J. Struct. Chem. 9, 286 (1990).

    Google Scholar 

  4. Wang RuiYao, Jin ZhongSheng, and Ni JiaZuan:Chinese J. Struct. Chem. 10, 20 (1991).

    Google Scholar 

  5. R.D. Rogers, A.N. Rollins, R.D. Etzenhouser, and R.F. Henry:J. Incl. Phenom. 8, 375 (1990).

    Google Scholar 

  6. Mao JiangGao, Jin ZhongSheng, and Yu FengLan:Chinese J. Struct. Chem. (accepted) (1993).

  7. Yu FengLan, Jin ZhongSheng, Hu NingHai, and Ni JiaZuan:Chinese J. Appl. Chem. 5, 42 (1983).

    Google Scholar 

  8. J.C.G. Bunzli, B. Klein, D. Wessner et al.Inorg. Chim. Acta 59, 269 (1982).

    Google Scholar 

  9. R.D. Rogers and L.K. Kurihara:J. Incl. Phenom. 4, 351 (1986).

    Google Scholar 

  10. R.D. Rogers and Luis Nunez:Inorg. Chim. Acta 172, 173 (1990).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Laboratory of Rare Earth Chemistry and Physics, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 130022, Changchun, P. R. China

    Jianggao Mao, Zhongsheng Jin & Jiazuan Ni

Authors
  1. Jianggao Mao
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Zhongsheng Jin
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Jiazuan Ni
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Supplementary Data relating to this article are deposited with the British Library as Supplementary Publication No. 82158 (27 pages).

Rights and permissions

Reprints and permissions

About this article

Cite this article

Mao, J., Jin, Z. & Ni, J. Crystal structure of [Yb (NO3)3 (phen) (H2O)] · (12-crown-4). J Incl Phenom Macrocycl Chem 16, 267–272 (1993). https://doi.org/10.1007/BF00708796

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00708796

Key words

Search

Navigation