Abstract
Calcium carbonate-filled polypropylene composites were processed on two different highintensity mixing devices. The resulting relationships between morphology, processing conditions and mechanical properties of these composites were studied using an electron microscope with an image-analysis system and impact and tensile testing. Only under more extreme conditions did the recently developed turbine mixer give as good a dispersion as the classical Banbury-style mixer. Relatively small additions of the filler resulted in small increases in absorbed impact energy. Semi-quantitative information about the randomness achieved in the mixing process was obtained using a dilation/counting procedure and computer-derived spatial images. Object-specific parameters such as the percentage of objects greater than 1 μm in size give good correlation with the mechanical properties of the mixture.
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References
S. N. Maiti and P. K. Mahapatro, J. Appl. Polym. Sci. 42 (1991) 3101.
A. M. Riley, C. D. Paynter, P. M. McGenity and J. M. Adams, Plast. Rubb. Proc. Appl. 14 (1990) 85.
S. F. Xavier, J. M. Schultz and K. Friedrich, J. Mater. Sci. 25 (1990) 2411.
Y. Suetsugu, Intern. Polym. Proc. 5 (1990) 3.
L. Chen, Y. Mai and B. Cotterell, Polym. Eng. Sci. 29 (1989) 505.
K. Mitsuishi, S. Kodama and H. Kawasaki, Ang,. Makr. Ch. 189 (1991) 13.
Idem, Polym. Eng. Sci. 25 (1985) 1069.
V. P. Chako, R. J. Farris and F. E. Karasz, J. Appl. Polym. Sci. 28 (1983) 2701.
T. Hayashi and T. Nishi, in Proceedings of International Conference on “Mechanical Behaviour of Materials VI”, Kyoto, 1991, p. 325.
V. Svehlova and E. Poloucek, Ang. Makr. Ch. 178 (1986) 197.
S. P. Rwei and I. Manas-Zloczower, Polym. Eng. Sci. 31 (1991) 558.
I. Manas-Zloczower and D. L. Feke, Intern. Polym. Proc. 4 (1989) 3.
N. Nakajiama and E. R. Harrel, Rubb. Chem. Technol. 57 (1984) 153.
D. Lyons and W. E. Baker, Intern. Polym. Proc. 5 (1990) 136.
Z. Tadmor and C. Gogos, “Principles of Polymer Processing” (Wiley, New York, 1979) p. 447.
W. Petruk in Proceedings of Short Course in Image Analysis Applied to Mineral and Earth Science, Ottawa, 1988 (Mineralogical Association of Canada, 1989) Vol. 16, Ch. 3.
J. C. Russ, “Computer Assisted Microscopy” (Plenum, New York, 1990).
B. B. Mandelbrot, “The Fractal Geometry of Nature’ (Freeman, New York, 1983).
B. Turcsanyi, B. Pukanszky and F. Tudos, J. Mater. Sci. Lett. 7 (1988) 160.
B. Pukanszky, F. Tudos, J. Jancar and J. Kolarik, J. Mater. Sci. Lett. 8 (1989) 1040.
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Herzig, R., Baker, W.E. Correlations between image-analysed morphology and mechanical properties of calcium carbonate-filled polypropylene. JOURNAL OF MATERIALS SCIENCE 28, 6531–6539 (1993). https://doi.org/10.1007/BF00356389
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DOI: https://doi.org/10.1007/BF00356389