Abstract
Oriented poly-p-phenylene sulphide (PPS) films (thickness 12 and 75 μm) and PPS powder were carbonized/graphitized after stabilizing by oxidation, in order to examine the effect of sulphur on graphitizability of the resulting carbons. The films and the powder resulted in carbons with a high and a low graphitizability respectively. An “in-plane oriented structure” of the PPS film was the most predominant factor to lead to a high graphitizability, and sulphur in the precursor did not lower the graphitizability when it was subjected to solid-phase carbonization. These phenomena are discussed on the basis of analytical data.
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References
A. Burger, E. Fitzer, M. Heym and B. Terwiesch, Carbon 13 (1975) 149;
Y. Hishiyama, S. Sanada, A. Yoshida and M. Inagaki, J. Mater. Sci. 23 (1988) 3272.
M. Murakami, H. Yasujima, Y. Yumoto, S. Mizogami and S. Yoshimura, Solid State Commun. 45 (1983) 1085.
T. Ohnishi, I. Murase, T. Noguchi and M. Hirooka, Synth. Met. 14 (1986) 207.
J. I. Kipling, P. V. Shooter and R. N. Young, Carbon 4 (1966) 333.
S. Otani and A. Oya, Kogyo Kagaku Zasshi 73 (1979) 493.
E. Fitzer and S. Weisenburger, Carbon 14 (1976) 195.
B. J. Tabor, E. P. Magre and J. Boon, Euro. Polymer J. 7 (1971) 1127.
F. Tuinstra and J. L. Koenig, J. Chem. Phys. 53 (1970) 1126.
G. F. L. Ehlers, K. R. Fisch and W. R. Powell, J. Polym. Sci. A-1 7 (1969) 2955.
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Oya, A., Arai, K. & Fujita, K. Carbonization and graphitization of poly-p-phenylene sulphide (PPS) film. Journal of Materials Science 29, 4477–4480 (1994). https://doi.org/10.1007/BF00376269
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DOI: https://doi.org/10.1007/BF00376269