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Peroxosalts initiated graft copolymerization of aniline onto wool fibre—a comparative kinetic study

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Abstract

Chemical grafting of aniline (ANI) onto wool fibre was carried out in aqueous acidic medium by using peroxosalts such as peroxodisulphate (PDS) and peroxomonosulphate (PMS) as an initiator for various [Monomer], [Initiator] and (fibre weight). It was observed that both Rh and Rg increased with increase in the concentration of each component. The chemical grafting was confirmed using FTIR spectroscopy, cyclic voltammetry (CV) and conductivity measurements.

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References

  1. A. Gopalan, T. Vasudevan, G. Paruthimal kalaignan, P. Manisankar, A. Ramasubramanian and S. S. Hariharan, J. Appl. Polym. Sci. 56 (1995) 1299.

    Google Scholar 

  2. T. Vasudevan, G. Paruthimal kalaignan, P. Manisankar, A. Ramasubramanian and S. S. Hariharan Idem., ibid. 56 (1995) 1715.

    Google Scholar 

  3. Y. Kawajara, M. Shioya, T. Kikutani and A. Takaku, J. Text. Inst. 88(1) (1997) 5.

    Google Scholar 

  4. M. Sacak and F. Oflaz, J. Appl. Polym. Sci. 50 (1993) 1909.

    Google Scholar 

  5. M. Sacak, F. Senkaya and M. Talu, ibid. 44 (1992) 1737.

    Google Scholar 

  6. A. Gopalan, T. Vasudevan, A. Ramasubramanian and S. S. Hariharan, Intern. J. Polymeric. Mater., to appear.

  7. R. Anbarasan, M. Sudha, T. Vasudevan and A. Gopalan, J. Text. Inst., communicated.

  8. S. P. Armes and J. F. Miller, Synth. Met. 22 (1988) 385.

    Google Scholar 

  9. A. Watanabe, K. Mori, Y. I. Wasak and Y. Nakamura, J. Chem. Soc. Chem. Commun. 3 (1987).

  10. H. Seuaua, T. Shimidzu and M. Honda, J. Chem. Soc. Chem. Commun. 132 (1989).

  11. L. T. Yu, M. S. Borreadon and R. Buvel, J. Polym. Sci. 10 (1987) 2931.

    Google Scholar 

  12. E. M. Genies, C. Tsintavis and A. A. Syed, Mol. Cryst. Liq. Cryst. 121 (1985) 181.

    Google Scholar 

  13. H. Yan and N. Toshima, Synth. Met. 69 (1995) 151.

    Google Scholar 

  14. N. Toshima, Makromol. Chem. Macromol. Symp. 59 (1992) 123.

    Google Scholar 

  15. M. A. Depaoli, E. R. Duek and M. A. Rodrigues, Synth. Met. 41(3) (1991) 973.

    Google Scholar 

  16. L. A. Prezyna and G. E. Wnek, ibid. 41(3) (1992) 979.

    Google Scholar 

  17. P. Punkka, J. Laakso and P. Kuivalaiven, ibid. 41(3) (1991) 983.

    Google Scholar 

  18. R. Anbarasan, T. Vasudevan and A. Gopalan, J. Appl. Polym. Sci. to appear.

  19. Idem., Intern. J. Polymeric Mater., to appear.

  20. R. Anbarasan, N. Muthumani, T. Vasudevan and A. Gopalan, Polymer, communicated.

  21. R. Anbarasan, T. Vasudevan and A. Gopalan, Polym. Int., to appear.

  22. Idem., Intern. J. Polym. Anal. Char., to appear.

  23. Idem., Eur. Polym. J., communicated.

  24. K. Tzou and R. V. Gregory, Synth. Met. 47(3) (1992) 267.

    Google Scholar 

  25. S. N. Bhadani and M. Kumari, J. Polym. Mater. 13 (1996) 61.

    Google Scholar 

  26. R. K. Samal, R. Samal and S. Send, ibid. 7 (1990) 175.

    Google Scholar 

  27. S. Lenka, P. C. Nayak and M. K. Mishra, J. Appl. Polym. Sci. 25 (1980) 1323.

    Google Scholar 

  28. M. K. Mishra, S. Lenka and K. Atanu, ibid. 25 (1981) 93.

    Google Scholar 

  29. Y. Wei, R. Hariharan and S. A. Patel, Macromolecules 23 (1990) 758.

    Google Scholar 

  30. Y. B. Shim, M. S. Won and S. M. Park, J. Electrochem. Soc. 137 (1990) 538.

    Google Scholar 

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Authors and Affiliations

  1. Department of Industrial Chemistry, Alagappa University, Karaikudi-, 630 003, Tamil Nadu, India

    R. Anbarasan & T. Vasudevan

  2. Department of Industrial Chemistry, Alagappa University, Karaikudi-, 630 003, Tamil Nadu, India

    A. Gopalan

Authors
  1. R. Anbarasan
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  2. T. Vasudevan
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  3. A. Gopalan
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Anbarasan, R., Vasudevan, T. & Gopalan, A. Peroxosalts initiated graft copolymerization of aniline onto wool fibre—a comparative kinetic study. Journal of Materials Science 35, 617–625 (2000). https://doi.org/10.1023/A:1004776427294

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  • DOI: https://doi.org/10.1023/A:1004776427294

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