Skip to main content
Log in

Diffusion of Cs+ and Zn2+ through Nafion-117 ion exchange membrane

  • Published:
Journal of Radioanalytical and Nuclear Chemistry Aims and scope Submit manuscript

Abstract

This paper discusses the diffusion of Cs+ and Zn2+ ions through Nafion-117 cation exchange membrane using radiotracer technique. The validity of the Donnan's equation is checked for these ions using65Zn and137Cs radiotracers. The paper also discusses the diffusion of Cl and I anions studied by using36Cl and131I radiotracers. The probable mechanism of diffusion of these anions in the presence of Zn2+ cations is suggested.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. F. Helfferich, Ion Exchange, McGraw Hill, New York, 1962.

    Google Scholar 

  2. K. Pyrzynska,Anal. Chim. Acta, 255 (1991) 169.

    Article  Google Scholar 

  3. J.A. Cox, T. Gray, K.S. Yoon, Y.T. Kim, Z. Twardowski,Analyst, 109 (1984) 1603.

    Article  Google Scholar 

  4. J.A. Koropchak, L. Allen,Anal. Chem., 61 (1989) 1410.

    Article  Google Scholar 

  5. R.M. Wallace,I & EC Process. Design and Develop., 6(4) (1967) 423.

    Google Scholar 

  6. R.S. Yeo, in: Perfluorinated Ionomer Membranes, A. Eisenberg and H.L. Yeager (ed.), ACS Symposium Series 180, American Chemical Society, Washington, 1982, p. 453.

    Google Scholar 

  7. A.J. Appleby and R.L. Toulkes (ed.), Fuel Cell Handbook, Van Norsrand, New York, 1989.

    Google Scholar 

  8. A. Eisenberg and H.L. Yeager (ed.) Perfluorinated Ionomer Membranes, ACS Symposium Series 180, American Chemical Society, Washington, 1982.

    Google Scholar 

  9. T.D. Gierke, W.Y. Hsu, in: Perfluorinated Ionomer Membranes, A. Eisenberg and H.L. Yeager (ed.) ACS Symposium Series 180, American Chemical Society, Washington, 1982, p. 283.

    Google Scholar 

  10. M.V. Coulter, Modern Chlor Alkali Technology, Society of Chemical Industry, Ellis Horwood Limited, Chichester, England, 1980.

    Google Scholar 

  11. M.C. Shen, A. Eisenberg, in: Progress in Solid State Chemistry, Vol. 3, Pergamon Press, New York, 1966, p. 407.

    Google Scholar 

  12. M. Falk,Can. J. Chem., 58 (1980) 1495.

    Google Scholar 

  13. E.J. Roche, M. Pineri, R. Duplessix, A.M. Levelut,J. Polym. Sci. Polym. Phys. Ed., 19 (1981) 1.

    Article  Google Scholar 

  14. S. Quezado, J.C.T. Kwak, M. Falk,Can. J. Chem., 62 (1984) 958.

    Google Scholar 

  15. M. Lopez, B. Kipling H.L. Yeager,Anal. Chem., 49(4) (1977) 629.

    Article  Google Scholar 

  16. F.G. Will,J. Electrochem. Soc., 126 (1) (1979) 36.

    Google Scholar 

  17. H.L. Yeager, B. Kipling,J. Phys. Chem., 83 (14) (1979) 1836.

    Article  Google Scholar 

  18. W.J. Blaedel, E.L. Christensen,Anal. Chem., 39 (11) (1967) 1262.

    Article  PubMed  Google Scholar 

  19. A. Herrera, H.L. Yeager,J. Electrochem. Soc., 134 (10) (1987) 2446.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Sodaye, H.S., Pujari, P.K., Goswami, A. et al. Diffusion of Cs+ and Zn2+ through Nafion-117 ion exchange membrane. Journal of Radioanalytical and Nuclear Chemistry Letters 214, 399–409 (1996). https://doi.org/10.1007/BF02163827

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02163827

Keywords

Navigation