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Synthesis, infrared spectra and thermoanalytical properties of transition metal sulfite hydrazine hydrates

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Abstract

Transition metal sulfite hydrazine hydrates, MSO3·xN2H4·yH2O whereM=Mn, Fe, Co, Ni and Zn have been prepared and characterized by chemical analysis, infrared spectra, thermoanalytical and combustion studies. The colours,x andy parameters of the complexes varied depending upon the preparation conditions. Thermal decomposition characteristics differ from metal to metal yielding metal oxides at relatively low temperatures.

Zusammenfassung

Mittels chemischer Analyse, IR-Spektren, thermoanalytischen und Verbrennungsstudien wurden die Hydrazinhydrate der hergestellten Übergangsmetallsulfite MSO3·xN2H4·yH2O mitM=Mn, Fe, Co, Ni und Zn beschrieben. Farbe sowie die Parameterx undy der Komplexe hängen von den Herstellungsbedingungen ab. Die thermische Zersetzung, bei der bei relativ niedrigen Temperaturen Metalloxide entstehen, ist von Metall zu Metall verschieden.

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Authors and Affiliations

  1. Department of Chemistry, Goa University Bambolim, 403 005, Goa, India

    Jayant S. Budkuley & K. C. Patil

  2. Department of Inorganic and Physical Chemistry, Indian Institute of Science, 560 012, Bangalore, India

    K. C. Patil

Authors
  1. Jayant S. Budkuley
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  2. K. C. Patil
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Budkuley, J.S., Patil, K.C. Synthesis, infrared spectra and thermoanalytical properties of transition metal sulfite hydrazine hydrates. Journal of Thermal Analysis 36, 2583–2592 (1990). https://doi.org/10.1007/BF01913655

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  • DOI: https://doi.org/10.1007/BF01913655

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