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Thermal Behaviour of Transition Metal-Containing Zirconium Phosphate

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Abstract

The thermal behaviour of Co(II), Ni(II) and Zn(II)-containing zirconium phosphate of α type was investigated. XRPD analysis revealed that, for the samples containing Co(II) or Ni(II), the first reflection of the solid phase is split into a doublet. In contrast, when Zn(II) is present, a single solid phase system is formed. The thermal behaviour of the materials followed this sequence. For the samples containing Co(II) or Ni(II), phase-transition processes were found and there was also a loss of crystal water, but for the sample containing Zn(II) there was only one endothermic effect, which corresponded to the decomposition of phosphate groups.

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Authors and Affiliations

  1. Institute of Isotope and Surface Chemistry, Chemical Research Centre of the Hungarian Academy of Sciences, H-1525, Budapest, P.O. Box 77

    L. Szirtes, A. M. Szeleczky & A. O. Rajeh

  2. Department of Nuclear Chemistry, Eötvös Loránd University, H-1518, Budapest, P.O. Box 32, Hungary

    E. Kuzmann

Authors
  1. L. Szirtes
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  2. A. M. Szeleczky
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  3. A. O. Rajeh
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  4. E. Kuzmann
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Szirtes, L., Szeleczky, A.M., Rajeh, A.O. et al. Thermal Behaviour of Transition Metal-Containing Zirconium Phosphate. Journal of Thermal Analysis and Calorimetry 56, 447–451 (1999). https://doi.org/10.1023/A:1010183609021

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