Abstract
While the chemistry of polyoxoanions has been extensively studied, the related polyoxoalkoxide clusters remain relatively unexplored. Recent investigations into the coordination chemistry of polyoxoanions with alkoxide ligands demonstrate the existence of a rich structural chemistry which is now emerging. The introduction of alkoxide ligands into polyoxoanion cores significantly expands the structural diversity of the cluster types and allows the isolation not only of fully-oxidized cores with all metal centers possessing d0 electronic configurations but of fully-reduced and mixed valence systems.
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N. N. Greenwood and A. Earnshaw:Chemistry of the Elements, Pergamon Press, New York (1984).
M. T. Pope:Heteropoly and Isopoly Oxometalates, Springer-Verlag, New York (1983).
M. T. Pope: inComprehensive Coordination Chemistry, eds. G. Wilkinson and J. A. McCleverty, Pergamon Press, Oxford, vol. 3, p. 1023 (1987).
M. T. Pope, A. Müller:Angew. Chem., Int. Ed. Engl. 30, 29 (1991).
K.-H. Tytko and O. Glemser:Adv. Inorg. Chem. Radiochem. 19, 239 (1976).
T. J. R. Weakly:Structure and Bonding (Berlin) 18, 131 (1974); P. A. Tsigdinos:Topics Curr. Chem. 76, 1 (1978).
I. M. Campbell:Catalysis at Surfaces, Chapman and Hall, New York (1988).
R. K. Grasselli and J. F. Brazdil:Solid State Chemistry in Catalysis, ACS Symposium Series,279 (1985).
M. Misono:Catal. Rev.-Sci. Eng. 29, 269 (1987).
J. B. Moffat:Chem. Eng. Commun. 83, 9 (1989).
S. Ahmed and J. B. Moffat:Appl. Catal. 40, 101 (1988).
R. Newmann and M. Lissel:J. Org. Chem. 54, 4607 (1989).
E. Papaconstantinou:Chem. Soc. Rev. 18, 1 (1989).
T. Yamase:Polyhedron 5, 79 (1986).
R. C. Chambers and C. L. Hill:J. Am. Chem. Soc. 112, 8427 (1990); R. F. Renneke, M. Pasquali, and C. L. Hill:J. Am. Chem. Soc. 112, 6585 (1990); T. P. Snyder and C. G. Hill:Catal. Rev.-Sci. Eng. 31, 43 (1989).
B. El Ali, J.-M. Brigeault, J. Mercier, J. Martin, C. Martin, and O. Convert:J. Chem. Soc. Chem. Commun. 825 (1989).
H. J. Sanders:Chem. Eng. News 26 (1984).
W. Heywang and H. Thomann:Am. Rev. Mater. Sci. 14, 27 (1984).
C. G. Hubert-Pfalzgraf:New J. Chem. 11, 663 (1987).
D. R. Ulrich:Chem. Eng. News 28 (1990).
T. Shimidzu, A. Ohtani, M. Aiba, and K. Honda:J. Chem. Soc., Faraday Trans. 1, 3941 (1988).
M. Tatsumisago and T. Minomi:J. Am. Chem. Soc. 72, 484 (1989).
L. Ouahab, M. Benchaif, and D. Grandjean:C.R. Acad. Sci. Sec. 2, 307, 749 (1988).
H.T. Evans and S. Landergran: InHandbook of Geochemistry, ed. K. B. Wedepohl, Springer-Verlag, Berlin (1978).
H. T. Evans and J. S. White, Jr.:Min. Rec. 18, 333 (1987).
P. T. Pienkos and W. J. Brill:J. Bacteriol. 145, 743 (1981).
D. Dormont, B. Spire, F. Barre-Sinoissi, L. Montagnier, and J. C. Chermann:Ann. Int. Pasteur/Virol. 136E, 75 (1985).
T. Yamase, H. Fujita, and K. Fukushime:Inorg. Chim. Acta 151, 15 (1988).
F. Bussereau, M. Picard, J. Blancou, and P. Suveau:Acta Virol. 32, 33 (1988).
C. L. Hill, M. S. Weeks, and R. F. Schinazi:J. Med. Chem. 33, 2767 (1990).
Characterization of Heterogeneous Catalysts, ed. F. Delanny, Marcel Dekker, New York (1984).
V. W. Day and W. G. Klemperer:Science 228, 533 (1985).
V. W. Day, W. G. Klemperer, C. Schwartz, and R.-C. Wang: inSurface Organometallic Chemistry: The Molecular Approach to Surface Science and Catalysis, eds. J.M. Bassetet al., Kluwer, Dordrecht, Holland (1988), p. 173.
For examples of polyoxomolybdate coordination compounds see: E. M. McCarron, III and R. C. Harlow:J. Am. Chem. Soc. 105, 6179 (1983).
A. J. Wilson, W. T. Robinson, and C. J. Wilkins:Acta Cryst. C39, 54 (1983).
S. Liu, S. N. Shaikh, and J. Zubieta:Inorg. Chem. 26, 4303 (1987).
L. Ma, S. Liu, and J. Zubieta:Inorg. Chem. 28, 175 (1989).
W. G. Klemperer, V. U. Mainz, R.-C. Wang, and S. Yang: 3rd Chem. Conf. North America, Toronto (June 1988):Inorg. Abstr. 265.
V. W. Day, W. G. Klemperer, and C. Schwartz:J. Am. Chem. Soc. 109, 6030 (1987).
V. W. Day, M. F. Fredrich, W. G. Klemperer, and R.-S. Liu:J. Am. Chem. Soc. 101, 491 (1979).
V. W. Day, M. R. Thompson, W. G. Klemperer, and R.-S. Liu:J. Am. Chem. Soc. 102, 5971 (1980).
S. Liu, S. N. Shaikh, and J. Zubieta:Inorg. Chem. 27, 3064 (1988).
Q. Chen, S. Liu, H. Zhu, and J. Zubieta:Polyhedron 8, 2915 (1989).
For examples of polyoxovanadate coordination compounds see: H. Riskamp, P. Gietz, and R. Mattes:Chem. Ber. 109, 2090 (1976).
D. D. Heinrich, K. Folting, W. E. Streib, J. C. Huffman, and G. Christou:J. Chem. Soc. Chem. Comm. 1411 (1989).
D. Rehder, W. Priebsch, and M. von Olynhansen:Angew. Chem., Int. Ed. Engl. 28, 1221 (1989).
Q. Chen, S. Liu, and J. Zubieta:Inorg. Chem. 28, 4433 (1989).
Q. Chen and J. Zubieta:Inorg. Chem. 29, 1456 (1990).
V. W. Day, W. G. Klemperer, and O. M. Yaghi:J. Am. Chem. Soc. 111, 5959 (1989).
V. W. Day, M. F. Fredrich, W. G. Klemperer, and W. Shum:J. Am. Chem. Soc. 99, 6146 (1977).
J. Fuchs and H. Harth:Angew. Chem., Int. Ed. Engl. 15, 375 (1976); W. G. Klemperer and W. Shum:J. Am. Chem. Soc. 98, 8291 (1976).
V. W. Day, W. G. Klemperer, and O. M. Yaghi:J. Am. Chem. Soc. 111, 4518 (1989).
V. W. Day, W. G. Klemperer, and D. J. Maitlis:J. Am. Chem. Soc. 109, 2991 (1987).
R. D. Adams, W. G. Klemperer, and R.-S. Liu:J. Chem. Soc., Chem. Commun. 256 (1979).
E. M. McCarron, III, J. F. Whitney, and D. O. Chase:Inorg. Chem. 23, 3276 (1984).
J. W. Johnson, A. J. Jacobson, S. M. Rich, and J. F. Brody:J. Am. Chem. Soc. 103, 5246 (1981).
T.-C. Hsieh and J. Zubieta:Inorg. Chem. 24, 1287 (1985).
T.-C. Hsieh and J. Zubieta:Polyhedron 5, 309 (1985).
T.-C. Hsieh and J. Zubieta:Polyhedron 5, 1655 (1985).
S. N. Shaikh and J. Zubieta:Inorg. Chem. 25, 4613 (1986).
T.-C. Hsieh and J. Zubieta:J. Chem. Soc. Chem. Commun. 1749 (1985).
T.-C. Hsieh, S. N. Shaikh and J. Zubieta:Inorg. Chem. 26, 4079 (1987).
S. N. Shaikh and J. Zubieta:Inorg Chim. Acta 121, 243 (1986).
S. Liu and J. Zubieta:Polyhedron 7, 401 (1988).
Q. Chen, S. Liu, and J. Zubieta:Inorg. Chim. Acta 164, 115 (1989).
H. Kang, S. Liu, S. N. Shaikh, T. Nicholson, and J. Zubieta:Inorg. Chem. 28, 920 (1989).
D. C. Bradley, R. C. Mehrotra, D. P. Gaur:Metal Alkoxides, Academic Press, New York (1978).
R. C. Mehrotra:Transition Metal Alkoxides, inAdvances in Inorg. Radiochem., eds. H. G. Emeleus and A. G. Sharpe, Academic Press, New York,26, 269 (1983).
M. H. Chisholm: inChemistry Toward the 21st Century, ACS, Washington, D.C. (1983), p. 243.
M. H. Chisholm: inComprehensive Coordination Chemistry, eds. G. Wilkinson, J. A. McCleverty, Pergamon Press, Oxford (1987).
P. C. Bradley:Chem. Rev. 89, 1317 (1989).
K. G. Caulton and J. G. Hubert-Pfalzgraf:Chem. Rev. 90, 969 (1990).
P. P. Power:Comments Inorg. Chem. 8, 177 (1989).
I. P. Rothwell:Acc. Chem. Res. 21, 153 (1988).
R. E. Lar Pointe, P. T. Wolczanski, J. F. Mitchell:J. Am. Chem. Soc. 108, 6382 (1986).
L. G. McCullough, P. R. Schrock, J. C. Dewan, and J. C. Murdzek:J. Am. Chem. Soc. 107, 5907 (1985).
W. E. Buhro and M. H. Chisholm:Adv. Organomet. Chem. 27, 311 (1987).
H. E. Bryndze and W. Tam:Chem. Rev. 26, 269 (1983).
See for example: C. E. Rehberg:Org. Syn. 26, 18 (1946).
R. C. Mehrotra:J. Non-Cryst. Solids 100, 1 (1988).
C. J. Brinker:J. Non-Cryst. Solids 100, 31 (1988).
M. Guglidmin and G. Cartman:J. Non-Cryst. Solids 100, 16 (1988).
H. Schmidt:J. Non-Cryst. Solids 100, 51 (1988).
C. Sanchez, J. Livage, M. Henry, and F. Babonneau:J. Non-Cryst. Solids 100, 65 (1988).
C. N. R. Rao and J. Gopalakrishnan:Acc. Chem. Res. 20, 228 (1987).
F. Aldinger and H.-J. Kalz:Angew. Chem., Int. Ed. Engl. 26, 37 (1987).
D. R. Ulrich: inTransformation of Organometallics into Common and Exotic Materials: Design and Activation, ed. R. Laine, Martinus Nijhoff, Dordrecht (1988), p. 207.
H. Dislich:Angew. Chem., Int. Ed. Engl. 10, 363 (1971).
V. W. Day, T. A. Eberspacher, W. G. Klemperer, C. W. Park, and F. S. Rosenburg:J. Am. Chem. Soc. 113, 8190 (1991).
K. Watenpaugh and C. N. Cauglan:J. Chem., Soc. Chem. Commun. 67 (1967).
D. C. Bradley, M. B. Hursthouse, and P. F. Rodesila:J. Chem. Soc., Chem. Commun. 1112 (1968).
D. L. Kepert:The Early Transition Metals, Academic Press, London (1972).
J. F. Keggin:Nature 131, 908 (1933).
See for example: J. A. Hollingshead and R. E. McCarly:J. Am. Chem. Soc. 112, 7402 (1990).
K. Hegetschweiler, H. Schmalle, H. M. Streit, and W. Schneider:Inorg. Chem. 29, 3625 (1990).
K. G. Caulton, M. H. Chisholm, S. R. Drake, and J. C. Huffman:J. Chem. Soc., Chem. Commun. 1498 (1990).
K. G. Caulton, M. H. Chisholm, S. R. Drake, and K. Folting:J. Chem. Soc., Chem. Commun. 1349 (1990).
D. C. Bradly, H. Chudzynaka, D. M. Frigo, M. E. Hammond, M. B. Hursthouse, and M. A. Mazid:Polyhedron 9, 719 (1990).
W. J. Evans and M. S. Sollberger:J. Am. Chem. Soc. 108, 6095 (1986).
M. H. Chisholm, J. C. Huffman, C. C. Kirkpatrick, J. Leonelli, and K. Folting:J. Am. Chem. Soc. 103, 6093 (1981).
H. Kang, S. Liu, S. N. Shaikh, T. Nicholson, and J. Zubieta:Inorg. Chem. 28, 920 (1989).
M. H. Chisholm, K. Folting, J. C. Huffman, and C. C. Kirkpatrick:Inorg. Chem. 23, 1021 (1984).
M. Yu Antipis, L. P. Didenko, L. M. Kachapina, A. E. Shilov, A. K. Shilova, and Y. T. Struchkov:J. Chem. Soc., Chem. Commun. 1467 (1989).
Q. Chen and J. Zubieta: unpublished results.
A. I. Yanovskii, N. Turova, E. P. Turevskeya, and Yu T. Stuchkov:Koord. Khim. 8, 153 (1982).
R. Papiernik, L. G. Hubert-Pfalzgraf, J.-C. Daran, and Y. Jeannin:J. Chem. Soc., Chem. Commun. 695 (1990).
C. Chandler, G. D. Fallon, and B. O. West:J. Chem. Soc., Chem. Commun. 1063 (1990).
L. L. Hench and J. K. West:Chem. Rev. 90, 33 (1990).
S. Liu, S. N. Shaikh, and J. Zubieta:Inorg. Chem. 26, 4305 (1987).
W. N. Lipscomb:Inorg. Chem. 4, 132 (1965).
Q. Chen, S. Liu, and J. Zubieta:Inorg. Chim. Acta 162, 163 (1989).
A. Goiffen and B. Spinner:Rev. Chim. Minérale 12, 316 (1975).
D. L. Kepert:Inorg. Chem. 8, 1556 (1969).
Y. Du, A. L. Rheingold, and E. A. Maata:J. Am. Chem. Soc. 114, 345 (1992).
H. Vivier, J. Bernard, and H. Djomaa:Rev. Chim. Minérale 14, 584 (1977).
H. T. Evans, Jr.:J. Am. Chem. Soc. 90, 3275 (1968).
A. Müllen:Angew. Chemie 76, 588 (1964).
M. F. Belicchi, G. G. Fava, and C. Pelizzi:J. Chem. Soc., Dalton Trans. 65 (1983).
J. A. Beaver and M. G. B. Drew:J. Chem. Soc., Dalton Trans. 1376 (1973).
S. Lincoln and S. A. Koch:Inorg. Chem. 25, 1594 (1986).
S. Liu and J. Zubieta:Polyhedron 8, 537 (1989).
Q. Chen, S. Liu, and J. Zubieta:Inorg. Chim. Acta 164, 115 (1989).
S. Liu, X. Sun, and J. Zubieta:J. Am. Chem. Soc. 110, 3324 (1988).
S. Liu, X. Sun, and J. Zubieta: unpublished results; X. Sun: Masters Dissertation, SUNY at Albany (1988).
I. W. Boyd, I. G. Dance, A. E. Landers, and A. G. Wedd:Inorg. Chem. 18, 1875 (1979).
T.-C. Hsieh, T. Nicholson, and J. Zubieta:Inorg. Chem. 27, 241 (1988).
I. Buchanan, W. Clegg, C. D. Garner, and G. M. Sheldrick:Inorg. Chem. 22, 3657 (1983).
M. Yu Antipin, L. P. Didenko, L. M. Kachapina, A. E. Shilov, A. K. Shilova, and Y. T. Struchkou:J. Chem. Soc., Chem. Commun. 1467 (1989).
M. B. Robin and P. Day:Adv. Inorg. Chem. Radiochem. 10, 247 (1967).
Q. Chen, S. Liu, and J. Zubieta:Angew. Chem., Int. Ed. Engl. 27, 1724 (1988).
B. Spivack and Z. Dori:Coord. Chem. Rev. 17, 99 (1975).
E. Stiefel:Prog. Inorg. Chem. 22, 1 (1977).
O. J. Darensbourg, R. L. Gray, and T. Delord:Inorg. Chim. Acta 98, 239 (1985).
S. N. Shaikh and J. Zubieta:Inorg. Chem. 25, 4615 (1986).
J. R. Dilworth:Coord. Chem. Rev. 21, 29 (1976).
M. W. Bishop, J. Chatt, J. R. Dilworth, M. R. Hursthouse, and M. Motevalli:J. Chem. Soc., Dalton Trans. 1600 (1979).
B. J. Burt, J. R. Dilworth, G. J. Leigh, and J. A. Zubieta:J. Chem. Soc., Dalton Trans. 2295 (1982).
J. R. Dilworth, J. Hutchinson, L. Throop, and J. Zubieta:Inorg. Chim. Acta 79, 208 (1983).
J. Chatt, B. A. L. Crichton, J. R. Dilworth, P. Dahlstrom, R. Gutkoska, and J. Zubieta:Inorg. Chem. 21, 2383 (1982).
B. A. L. Crichton, J. R. Dilworth, P. Dahlstrom, and J. Zubieta:Trans. Met. Chem. (Weinheim, Germany)5, 316 (1980).
S. N. Shaikh and J. Zubieta:Inorg. Chim. Acta 121, 243 (1986).
D. Attanasio, V. Fares, and P. Imperatori:J. Chem. Soc., Chem. Commun. 1476 (1986).
S. N. Shaikh and J. Zubieta:Inorg. Chem. 27, 1896 (1988).
S. Liu and J. Zubieta:Polyhedron 7, 401 (1988).
H. Kang, S. Liu, S. N. Shaikh, and J. Zubieta:Inorg. Chem. 28, 920 (1989).
P. Gouzerh, Y. Jeannin, A. Proust, and F. Robert:Angew. Chem., Int. Ed. Engl. 28, 1364 (1989).
A. Proust, P. Gouzerh, F. Robert, Y. Jeannin, Q. Chen, and J. Zubieta:SFC91 - 4 e Congrès de La Soc. Française de Chim., Strasbourg (1991), pp. 136–7.
J. Fuchs, H. Harth, W. Schiller, and U. Gerlach:Acta Cryst. B32, 740 (1975).
See for example: V. McKee and C. J. Wilkins:J. Chem. Soc., Dalton Trans. 523 (1987); R. N. Hilder and C. J. Wilkins:J. Chem. Soc., Dalton Trans. 495 (1984); W. Shum:Inorg. Chem. 25, 4329 (1986).
D. C. Kepert:Inorg. Chem. 8, 1556 (1969).
K. H. Tytko and O. Glemser:Adv. Inorg. Chem. Radiochem. 19, 239 (1976).
C. B. Knobler, B. R. Penfold, W. T. Robinson, C. J. Wilkins, and S. M. Yong:J. Chem. Soc., Dalton Trans. 284 (1980).
E. Gumaer, K. Lettko, L. Ma, D. Macherone, and J. Zubieta:Inorg. Chim. Acta 179, 47 (1991).
S. Liu, L. Ma, D. McGowty, and J. Zubieta:Polyhedron 9, 1541 (1990).
L. Ma, S. Liu, and J. Zubieta:Inorg. Chem. 28, 175 (1989).
A. J. Wilson, W. T. Robinson, and C. J. Wilkins:Acta Crystallogr. Sect. C39, 54 (1983).
R. J. Butcher and B. R. Penfold:J. Cryst. Mol. Struct. 6, 13 (1976).
F. A. Cotton and R. C. Elder:Inorg. Chem. 3, 397 (1964).
J. J. Park, M. D. Glick, and J. L. Hoard:J. Am. Chem. Soc. 91, 301 (1969).
W. Hermann and K. Wieghardt:Polyhedron 5, 513 (1986).
J. L. Garin and J. A. Constamanga:Act. Crystallogr. Sect. C44, 779 (1988); P. K. Bharadwaj, Y. Ohashi, Y. Sasada, Y. Sasaki, and T. Yamase:Acta Crystallogr.Sect. C 42, 545 (1986).
E. M. McCarron, III and R. L. Harlow:J. Am. Chem. Soc. 105, 6179 (1983).
L. Ma, S. Liu, and J. Zubieta:Inorg. Chem. 28, 175 (1989).
L. Ma, S. Liu, and J. Zubieta:J. Chem. Soc., Chem. Commun. 440 (1989).
V. W. Day, W. G. Klemperer, and O. M. Yaghi:J. Am. Chem. Soc. 111, 4519 (1989).
V. W. Day, W. G. Klemperer, and O. M. Yaghi:J. Am. Chem. Soc. 111, 5959 (1989).
V. W. Day, W. G. Klemperer, and D. J. Maltbie:J. Am. Chem. Soc. 109, 2991 (1987).
K. F. Jahr, J. Fuchs, and R. Oberhausen:Chem. Ber. 101, (1968).
J. Fuchs, S. Mahjour, and R. Palm:Z. Naturforsch. 31b, 544 (1976).
Q. Chen, S. Liu, and J. Zubieta:Inorg. Chem. 28, 4433 (1989).
D. C. Crans, R. W. Marshman, M. S. Gottlieb, O. P. Anderson, and M. M. Miller:Inorg. Chem. 31, 4939 (1992).
Q. Chen, J. Zubieta:Inorg. Chem. 29, 1456 (1990).
H. Chae, W. G. Klemperer, and V. W. Day:Inorg. Chem. 28, 1423 (1989).
Y. Hayashi, Y. Ozawa, and K. Isobe:Chem. Lett. 425 (1989).
M. I. Khan, Q. Chen, and J. Zubieta:Inorg. Chem. 31, 1556 (1992).
W. G. Klemperer, T. A. Marquart, and O. M. Yaghi:Angew. Chem., Int. Ed. Engl. 31, 49 (1992).
M. I. Khan, Q. Chen, D. P. Goshorn, H. Hope, S. Parkin, and J. Zubieta:J. Am. Chem. Soc. 114, 3341 (1992).
M. I. Khan and J. Zubieta:J. Am. Chem. Soc. 114, 10058 (1992).
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Zubieta, J. Polyoxoalkoxy molybdenum and vanadium clusters. Mol Eng 3, 93–120 (1993). https://doi.org/10.1007/BF00999626
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DOI: https://doi.org/10.1007/BF00999626