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Electrocatalytic properties of the Ti(OH)3−Mo(III) system in the reduction of molecular nitrogen

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Abstract

Electrochemical reduction studies of dinitrogen catalyzed by Ti(OH)3−Mo(III) in an alkaline methanol solution on a mercury cathode show that the maximum yield of hydrazine (4%) and ammonia (43%) is observed at 0.5 mA/cm2 current density. In experimental conditions it corresponds to the zero-charge potential of sodium amalgam (−1.86 V).

Abstract

при исследовании злектрохимического восстановления азота на ртутном катоде, катализируемого гидроокисью T (OH)3−Mo(III), найдено, что максимальный выход по току аммиака (43%) и гидразина (4%) наблюдается при плотности тока 0.5 mA/cm2, что в условиях эксперимента соответсвует потенциалу нулевого заряда амальгамы натрия.

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Authors and Affiliations

  1. Institute of General and Inorganic Chemistry, Kiev

    A. V. Gorodyskii, V. V. Danilin, O. N. Efimov, N. E. Nechaeva & V. N. Tsarev

  2. Division of the Institute of Chemical Physics, Chernogolovka, USSR

    A. V. Gorodyskii, V. V. Danilin, O. N. Efimov, N. E. Nechaeva & V. N. Tsarev

Authors
  1. A. V. Gorodyskii
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  2. V. V. Danilin
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  3. O. N. Efimov
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  4. N. E. Nechaeva
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  5. V. N. Tsarev
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Gorodyskii, A.V., Danilin, V.V., Efimov, O.N. et al. Electrocatalytic properties of the Ti(OH)3−Mo(III) system in the reduction of molecular nitrogen. React Kinet Catal Lett 11, 337–342 (1979). https://doi.org/10.1007/BF02079722

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  • DOI: https://doi.org/10.1007/BF02079722

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