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Isomerization of n-hexane over Pt/NH4NaY zeolite

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Abstract

Isomerization of n-hexane over Pt/NH4NaY follows the reaction scheme

k1, k2, kc linearly increase with increasing ammonia exchange degree in the zeolite and no significant changes in selectivity occur. During activation Al is partially removed from the lattice framework with the formation of HAlNaY.

Abstract

Изомеризация н-гексана на Pt/NH4NaY описывается следующей реакционной схемой.

Величины k1, k2 и kc линейно увеличиваются с увеличением степени обмена аммонийной группы в цеолите, а значительных изменений в селективности не наблюдалось. В течение активации Al частично удаляется из решетки с образованием HAlNaY.

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References

  1. F. Chevalier, M. Guinet, R. Maurel: Proc. Sixth Intern. Congr. on Catalysis, The Chemical Society, p. 478, London 1976.

  2. J. Weitkamp, H. Farag: Proc. Symposium on Zeolites, p. 327. Szeged (Hungary) 1978.

  3. M.A. Lanewala, P.E. Pickert, A.P. Bolton: J. Catal.,9, 95 (1967).

    Google Scholar 

  4. K.-H. Steinberg, H. Bremer, F. Hofmann, Ch.M. Minachev, R.V. Dimitriev, A.N. Detjuk: Z. anorg. allg. Chem.,404, 142 (1974).

    Google Scholar 

  5. H. Bremer, É. Miklósy, J. Papp and K.-P. Wendlandt: React. Kinet. Catal. Lett.,11, 45 (1979).

    Google Scholar 

  6. M.L. Poutsma: Zeolite Chemistry and Catalysis, p. 437. ACS, Washington 1976.

    Google Scholar 

  7. G.A. Olah: Angew. Chem.,85, 185 (1973).

    Google Scholar 

  8. B.S. Grennsfelder, H.H. Voge, G.M. Good: Ind. Eng. Chem.,41, 2573 (1949).

    Google Scholar 

  9. A.A. Vvedenskii: Termodinamicheskie raschety neftekhimicheskikh protsessov, Leningrad, 1960.

  10. A. Bielánski, J. Datka, A. Drelinkiewicz, A. Malecka: Proc. Symposium on Zeolites, p. 89. Szeged (Hungary) 1978.

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Bremer, H., Körnig, J., Reschetilowski, W. et al. Isomerization of n-hexane over Pt/NH4NaY zeolite. React Kinet Catal Lett 13, 209–215 (1980). https://doi.org/10.1007/BF02068568

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  • DOI: https://doi.org/10.1007/BF02068568

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