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Kinetics and thermodynamics of RuIII-EDTA complex catalyzed oxidation of diethylamine and triethylamine with molecular oxygen

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Abstract

The kinetics of oxidation of diethyl and triethylamine with molecular oxygen catalyzed by RuIII (EDTA-H) (H2O) complex has been studied at different temperatures (25–45 °C at pH 2.0 (μ=0.5 M KCl) as a function of amine concentration. The thermodynamic (ΔG0, ΔH0 and ΔS0) and the activation parameters (ΔH≠ and ΔS≠) for the reaction were computed.

Abstract

Кинетику окисления диэтил-и триэтиламинов молекулярным кислородом, катализированного комплексом RuIII (EDTA-H) (H2O) исследовали при различных температурах (25–45°C) и pH=2 (μ=0,5 M KCI) в зависимости от концентрации амина. Рассчитывали термодинамические параметры (ΔG0, ΔH0 и ΔS0), а также параметры активации реакции (ΔH≠ иΔS≠).

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Authors and Affiliations

  1. Central Salt and Marine Chemicals Research Institute, 364 002, Bhavnagar, India

    N. N. Taqui Khan, Debabrata Chatterjee, S. D. Bhatt, H. C. Bajaj & S. A. Mirza

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  1. N. N. Taqui Khan
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  2. Debabrata Chatterjee
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  3. S. D. Bhatt
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  4. H. C. Bajaj
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  5. S. A. Mirza
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Taqui Khan, N.N., Chatterjee, D., Bhatt, S.D. et al. Kinetics and thermodynamics of RuIII-EDTA complex catalyzed oxidation of diethylamine and triethylamine with molecular oxygen. React Kinet Catal Lett 44, 505–510 (1991). https://doi.org/10.1007/BF02073022

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  • DOI: https://doi.org/10.1007/BF02073022

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