Abstract
Nonempirical quantum-chemical calculations suggest a molecular model for oxygen adsorption on Lewis acid sites of zeolites. This adsorption complex is assumed to be capable of acting as an electron acceptor in the generation of benzene cation-radicals.
Abstract
На основе неэмпирических квантовохимических расчетов предложена молекулярная модель адсорбции кислорода на льюисовском кислотном центре цеолита. Сделано предположение о том, что такой адсорбционный комплекс способен выступать в качестве акцептора электрона в процессе образования катион-радикалов бензола.
Similar content being viewed by others
References
V.A. Barachevskii, A.N. Terenin: Optika Spectrosk.,17, 304 (1964).
M.I. Loktev, A.A. Slinkin: Usp. Khim.,45, 1594 (1976).
A.A. Slinkin, A.V. Kucherov: Usp. Khim.,54, 61 (1985).
J.C. Vedrine, A. Auroux, V. Bolis, P. Dejaife, C. Naccache, P. Wierzchowski, E.G. Deroune, J.B. Nagy, J.-P., Gilson, J.H.C. van Hoff, J.P. van den Berg, J. Wolthuizen: J. Catal., 59, 248 (1979).
A.A. Slinkin, A.V. Kucherov, D.A. Kondratiev, T.N. Bondarenko, A.M. Rubinstein, Kh.M. Minachev: Kinet. Katal., 27, 364 (1986).
V.L. Zholobenko, L.M. Kustov, V.B. Kazanskii: Kinet. Katal.,30, 901 (1989).
V.A. Bolshov, A.M. Volodin, A.G. Mariyasov, V.F. Yudanov, G.M. Zhidomirov: Dokl. Akad. Nauk SSSR,316, 141 (1991).
F.R. Chen, J.J. Fripiat: J. Phys. Chem.,96, 819 (1992).
A.G. Pelmenshchikov, E.A. Paukshtis, V.S. Stepanov, K.G. Ione, G.M. Zhidomirov, K.I. Zamaraev: Proceed. 9th Intern. Congr. Catal.,1, 404 (1988).
J. Sauer: Chem. Rev.,89, 199 (1989).
P.H. Kasai, R.J. Bishop: J. Phys. Chem.,77, 2308 (1973).
W.J. Mortier, J. Sauer, J.A. Lercher, N. Noller: J. Phys. Chem.,88, 905 (1984).
V.A. Bolshov, A.M. Volodin, G.M. Zhidomirov: Zeolite Catalysis for the Solution of Environmental Problems, Jaroslavl, Jan. 6–12, 1992. Novosibirsk, 1991. p. 45.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Yudanov, I.V., Zakharov, I.I. & Zhidomirov, G.M. On the generation mechanism of aromatic cation-radicals under adsorption on zeolites. React Kinet Catal Lett 48, 411–417 (1992). https://doi.org/10.1007/BF02162689
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF02162689