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Synthesis and 183W- and 51V-n.m.r. characterization of the α-GaW9V3O40 8− heteropolyanion

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Summary

The trivanadium-substituted heteropolytungstates M5H3GaW9V3O40·xH2O (M = Me4N, Et4N or K) have been prepared from their lacunary precursor, α-Na9GaW9O34H2, and characterized by elemental analysis, 51V- and 183W-n.m.r. spectroscopy, and electrochemistry. The 183W-n.m.r. spectrum of the title anion consists of two lines as expected for the C 3v structure of the trisubstituted A-α-Keggin anion.

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Authors and Affiliations

  1. Department of Chemistry, Northeast Normal University, 130024, Changchun, P. R. China

    Jingfu Liu, Xiaopeng Zhan, Yaguang Chen, Guoping Li & Jingping Wang

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  1. Jingfu Liu
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  2. Xiaopeng Zhan
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  3. Yaguang Chen
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  4. Guoping Li
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  5. Jingping Wang
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Liu, J., Zhan, X., Chen, Y. et al. Synthesis and 183W- and 51V-n.m.r. characterization of the α-GaW9V3O40 8− heteropolyanion. Transition Met Chem 20, 327–329 (1995). https://doi.org/10.1007/BF00139122

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  • DOI: https://doi.org/10.1007/BF00139122

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